Hydrothermal Synthesis and Characterization of a Novel Zinc Phosphite Compound

Abstract

Abstract: A novel 2D layer zinc phosphite compound Zn(DETA)Zn₂(HPO₃)₃ was hydrothermally synthesized.Single crystal X-ray diffraction reveals that the compound crystallized in the orthorhombic space group,Cmca,with a=1.889 25(1) nm,b=1.001 04(6) nm,c=1.630 32(8) nm,β=90°,V=3.083 3(3) nm³,Z=4,D_C=1.162 Mg·m^-3, R₁0.067 9 and wR₂0.158 3.The structure consists of {ZnO₄},{ZnO₂N₃} and {HPO₃} basic structural units.The vertexsharing {ZnO₄} and {HPO₃} units are connected forming an infinite 2D layer with four-,eight-and twelve-membered rings.It is very interesting that {ZnODETA}₂ dinuclear units are grafted in the twelve-membered ring channels.

Key words: Hydrothermal synthesis, Zinc phosphite, Crystal structure, Diethylenetriamine

CLC Number:

O614

TrendMD:

LIU Li, CHEN Chao, MENG He, ZHANG Feng, CUI Yan-Jie, PANG Wen-Qin . Hydrothermal Synthesis and Characterization of a Novel Zinc Phosphite Compound[J]. Chem. J. Chinese Universities, 2005, 26(10): 1783.

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Hydrothermal Synthesis and Characterization of a Novel Zinc Phosphite Compound

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