Synthesis and Crystal Structure of a 3D Inorganic-Organic Hybrid Compound [Zn3（BTC）2（H2O）3]n with Micropores

Abstract

Abstract: The title compound [Zn₃（BTC）₂（H₂O）₃]_n （BTC=1,3,5-benzenetricarboxylic acid） was synthesized under mild conditions and its crystal structure was determined by single crystal X-ray diffraction. The compound crystallizes in the cubic system and belongs to space group Fm-3m with a=2.662 6（3） nm ,V=18.877（4） nm³,Z=16,D_c=1.51 g/cm³,M_r=664.4,μ=0.198 mm^-1 , F（000）=852 ,R=0.062 5,wR=0.129 4. Its structure reveals that the title polymer is composed of dimeric zinc tetracarboxylate units,with a short Zn-Zn internuclear separation of 0.295 0（4） nm. The coordination of BTC ligands with Zn ions forms a 3D infinite framework with about 1.117 4 nm×1.327 4 nm pores along the [001],[100] and [010] direction.

Key words: Inorganic-organic hybrid framework, Crystal structure, Microporous compound

CLC Number:

O614

TrendMD:

FANG Qian-Rong, ZHU Guang-Shan, XIN Ming-Hong, ZHANG Da-Liang, SHI Xin, WU Gang, TIAN Ge, TANG Lu-Lu, XUE Ming, QIU Shi-Lun. Synthesis and Crystal Structure of a 3D Inorganic-Organic Hybrid Compound [Zn₃（BTC）₂（H₂O）₃]_n with Micropores[J]. Chem. J. Chinese Universities, 2004, 25(6): 1016.

References

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Synthesis and Crystal Structure of a 3D Inorganic-Organic Hybrid Compound [Zn₃（BTC）₂（H₂O）₃]_n with Micropores

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