Synthesis, Characterization and Co-template Role of a New 2-Dimensional Layered Aluminophosphate [Al6P8O32][(C2H5)2NHCH2CH2NH3]2[C2H5NH2CH2CH2NH2C2H5]

Abstract

Abstract: In this paper, a new layered aluminophosphate, [Al₆P₈O₃₂][(C₂H₅)₂NHCH₂CH₂NH₃]₂·[C₂H₅NH₂CH₂CH₂NH₂C₂H₅], was synthesized in the system Al(OPri)₃-H₃PO₄-N,N-diethyl-ethylenediamine-tetraglycol. Its structure was determined by single crystal X-ray diffraction analysis, and further characterized by XRD, ICP, TG and elemental analysis. The title compound crystallizes in monoclinic space group P2(1)/c , with a=0.909 45(2) nm, b=1.464 24(4) nm, c=1.875 72(5) nm, β=102.672(2)° and Z=4. Its structure constructed by the alternation of AlO₄ and PO₃(=O) units contains the 4,6,8-nets stacked in an ABAB sequence. Two kinds of organic cations, diprotonnated N,N-diethylethylenediamine and its rearranged product N,N′-diethylethylenediamine locate between the adjacent layers. Their co-templating role in the formation of the title compound was also studied in terms of host-guest interaction.

Key words: Layered aluminophosphate, Crystal structure, Co-template role, Host-guest interaction

CLC Number:

O614

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PENG Li, LI Ji-Yang, YU Ji-Hong, LI Yi, GUO Min, XU Ru-Ren. Synthesis, Characterization and Co-template Role of a New 2-Dimensional Layered Aluminophosphate [Al₆P₈O₃₂][(C₂H₅)₂NHCH₂CH₂NH₃]₂[C₂H₅NH₂CH₂CH₂NH₂C₂H₅][J]. Chem. J. Chinese Universities, 2004, 25(11): 1981.

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Synthesis, Characterization and Co-template Role of a New 2-Dimensional Layered Aluminophosphate [Al₆P₈O₃₂][(C₂H₅)₂NHCH₂CH₂NH₃]₂[C₂H₅NH₂CH₂CH₂NH₂C₂H₅]

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