Hydrothermal Synthesis and Characterizations of Na6In4[P7O24(OH)5]·4H2O

Abstract

Abstract: A new sodium indium phosphate Na₆In₄[P₇O₂4(OH)₅]·4H₂O was synthesized under a mild hydrothermal condition and its structure was determined by means of single-crystal X-ray diffraction methods. The title compound crystallizes in a hexagonal system, space group P6₃, with a= 0.950 23(5) nm, b=0.950 23(5) nm, c=1.694 2(2) nm, α=90°, β=90°, γ=120°, V=1.324 8(2) nm³, Z=8, structure refined to R=0.052 8 and wR=0.116 5 for₂ 134 independent observed reflections. The three-dimensional network structure consists of helical chains formed by apex-sharing polyhedra. The connection of the chains results in 4- and 8-polyhedral rings and cages centered by three indium metal connecting oxygen atoms formed by three 4-rings. The three-connected oxygen atom is firstly observed in indium phosphate systems.

Key words: Hydrothermal synthesis, Indium phosphate, Crystal structure

CLC Number:

O614

TrendMD:

MAO Shao-Yu, LI Man-Rong, CHEN Hao-Hong, HUANG Ya-Xi, MI Jin-Xiao, ZHAO Jing-Tai . Hydrothermal Synthesis and Characterizations of Na₆In₄[P₇O₂₄(OH)₅]·4H₂O[J]. Chem. J. Chinese Universities, 2004, 25(10): 1813.

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Hydrothermal Synthesis and Characterizations of Na₆In₄[P₇O₂₄(OH)₅]·4H₂O

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