Synthesis and Structure of a Novel Microporous Coordination Polymer [Co2(Hisor)2(4,4′-bpy)2(H2O)2]·4,4′-bpy Constructed by Hydrogen Bonds

Abstract

Abstract: A novel microporous coordination polymer [Co₂(Hisor)₂(4,4′-bpy)₂(H₂O)₂]·4,4′-bpy was synthesized by hydrothermal reaction and characterized by single crystal X-ray diffraction, elemental analysis and IR spectrum. The crystal belongs to the monoclinic system and space group is P2/n with a=1.040 6(3) nm, b=1.138 8(4) nm, c=1.854 7(6) nm, β=102.991(6)°, V= 2.141 6(12) nm³, Z=2, D_c=1.443 Mg/m³, M_r=930.62, μ=0.842 mm^-1, F(000)=952, GOF= 1.072, R=0.065 4, wR=0.146 8[I>2σ(I)]. There are two crystallographically independent Co(Ⅱ) ions in the title complex. The Hisor^2- and 4,4′-bpy link the metal ions into 2D grids with dimension of 0.522 3 nm×1.138 8 nm. There are O—H…O and N—H…O hydrogen bonds in the complex resulting in the formation of 3D network with 1D channels, in which are free 4,4′-bpy molecules.

Key words: Microporous coordination polymer, Crystal Structure, 5-Carboxyluracil

CLC Number:

O614

TrendMD:

SUN Chang-Yan, JIN Lin-Pei . Synthesis and Structure of a Novel Microporous Coordination Polymer [Co₂(Hisor)₂(4,4′-bpy)₂(H₂O)₂]·4,4′-bpy Constructed by Hydrogen Bonds[J]. Chem. J. Chinese Universities, 2004, 25(10): 1807.

References

Related Articles 15

[1]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[2]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[3]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[4]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[5]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[6]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[7]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[8]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[9]	TIAN Huan, ZHANG Menglong, WANG Lisha, TONG Bihai, ZHAO Zhuo. Synthesis of 4,13-Dithio Benzene and-18-Crown-6 and Its Selective Extractability on A $g + †$ [J]. Chem. J. Chinese Universities, 2018, 39(6): 1191.
[10]	ZHU Lei,HAN Junyan,CHANG Haizhen,QIU Yuyuan,ZHANG Yanan,PENG Danni,HU Wei,MIAO Shaobin. Different Pathways for the Cyclocondensation Reactions of 1,2-Diamine and 1,2-Diketone^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2686.
[11]	CHEN Qidan, TANG Junjie, FANG Qianrong. Highly Stable Fluorine Containing Hierarchical Porous Covalent Organic Framework^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2357.
[12]	LI Zheng, LI Rui, LI Xia. Synthesis, Crystal Structure and Fluorescent Properties of Transition Metal Complexes Constructed with 2-(3'-Carboxyphenoxy)benzoic Acid and N-Donor Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2363.
[13]	YUN Jixing,HU Zhili,LI Yumeng,JIN Jing,CHEN Chong,YAN Xin,LIU Yonghua,DING Yu,CHI Yuxian,NIU Shuyun. Synthesis, Structure and Photoelectric Property of A Series of Ni(Ⅱ) Complexes Constructed Through Aromatic Carboxylic Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2161.
[14]	TAN Ying, XIAO Mengwu, YE Jiao, HU Aixi, ZENG Ziqing, OU Xiaoming. Synthesis, Crystal Structure and Fungicidal Activity of (Z)-3,3-Dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-one O-[(5-Aryl-1,3,4-oxadiazol-2-yl)methyl] oxime [J]. Chem. J. Chinese Universities, 2017, 38(8): 1375.
[15]	WANG Qiushuang, ZHENG Xiaoli, QU Xianglong, LI Rui, LI Xia. Synthesis, Structure and Luminescence Property of Transition Metal Complexes with 1,3-Di(4-pyridyl)-propane and 1,2-Benzenedicarboxylic Acid^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1125.

Synthesis and Structure of a Novel Microporous Coordination Polymer [Co₂(Hisor)₂(4,4′-bpy)₂(H₂O)₂]·4,4′-bpy Constructed by Hydrogen Bonds

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments