Hydrothermal Synthesis and Structure of A Novel [Co(phen)(μ3-md)]n

Abstract

Abstract: Anovel 1-Dcompound, [[Co(phen)(μ₃-md)]_n] n, was hydrothermally synthesized and characterized by single crystal X-ray diffraction analysis, elemental analysis and IRspectra.This compound was crystallized in monoclinic system, space group P₂/C with a=0.8329(18) nm, b=1.04135(11) nm, c=1.8348(5) nm, β=100.436(18)°, Dc=1.706 mg/cm³, R₁= 0.0379, wR₂=0.0866. The 1-Ddouble-chain structure of the title compound is formed by benzene-1,3-dicarboxylate connected with three Co atoms.

Key words: [[Co(phen)(μ₃-md)]_n] n, Crystal structure, 1-D double-chain structure

CLC Number:

O614.81⁺2

TrendMD:

LI Chuan-Bi, ZHANG Li-Juan, SUN Ying-Hua, LI Yong, WANG Tie-Gang, XU Ji-Qing  . Hydrothermal Synthesis and Structure of A Novel [Co(phen)(μ₃-md)]_n[J]. Chem. J. Chinese Universities, 2003, 24(8): 1366.

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Hydrothermal Synthesis and Structure of A Novel [Co(phen)(μ₃-md)]_n

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