Synthesis and Characteristic of 3-D Inorganic-organic Hybrid Framework Microporous Material [Co3(BDC)3(EG)4]·2DMF

Abstract

Abstract: A 3-D inorganic-organic hybrid framework microporous material [CO₃(BDC)₃(EG)₄]·2DMF was synthesized under mild conditions and its crystal structure was determined bYUsing single crystal X-ray diffraction. The crystal structure was solved by a direct method and refined by full-matrix least-square method. The crystaLIs the triclinic system and belongs to space group P-1 with a=9.978(2) nm, b=11.223(2) nm, c=11.283(2) nm, α=102.26(3)°, β=113.52(3)°, γ=92.73(3)°, V=6.329(2) nm³, Z=1, D_c=1.565 Mg/m³, M_r=1 063.59, μ=1.183mm^-1, F(000)=541, GOF=1.024, R=0.044 2, _wR=0.124 9.

Key words: Crystal structure, Inorganic-organic hybrid framework, Microporous material

CLC Number:

O641

TrendMD:

FANG Qian-Rong, SHI Xin, XIN Ming-Hong, WU Gang, TIAN Ge, ZHU Guang-Shan, LI Ya-Feng, YE Ling, WANG Chun-Lei, ZHANG Zhen-Dong, TANG Lu-Lu, QIU Shi-Lun . Synthesis and Characteristic of 3-D Inorganic-organic Hybrid Framework Microporous Material [Co₃(BDC)₃(EG)₄]·2DMF[J]. Chem. J. Chinese Universities, 2003, 24(6): 980.

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Synthesis and Characteristic of 3-D Inorganic-organic Hybrid Framework Microporous Material [Co₃(BDC)₃(EG)₄]·2DMF

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