Hydrothermal Synthesis and Characterizaton of [CH3NH3][NH3(CH2)6NH3]H3[P2Mo2W16O62]·H2O

Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (5): 772.

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Hydrothermal Synthesis and Characterizaton of [CH₃NH₃][NH₃(CH₂)₆NH₃]H₃[P₂Mo₂W₁₆O₆₂]·H₂O

LIU Zong-Rui¹, WANG Li², CHEN Bao-Guo¹, XU Lin², WANG En-Bo², XING Yan³, JIA Heng-Qing³, LIN Yong-Hua³

1. College of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028043, China;
2. Faculty of Chemistry, Northeast Normal University, Changchun 130024, China;
3. Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2002-02-27 Online:2003-05-24 Published:2003-05-24

Abstract

Abstract: Anovel heteropoly tungstomolybdophosphate,[CH₃NH₃][NH₃(CH₂)₆NH₃]H₃[P₂Mo₂W₁₆O₆₂]·H₂O has been synthesized and characterized by elemental analysis, IR, TGA-DSC and single-crystal X-ray structure analysis. Crystal data; monoclinic, space group P2₁/m, a=1.2596(3) nm, b=1.8715(4) nm, c=l. 9816(4) nm, a=γ=90°, β=90. 16(3)° V=4. 671(2) nm³, Z=2, M_r= 4358. 66, D_c= 3. 100 g·cm^-3, μ=19. 978 mm^-1, F(000)=3792, R=0. 0835, R_w= 0. 2026. The structure analysis shows that a kind of micropore with size of 0. 7364 nm×0. 8354 nm was formed in the crystal structure.

Key words: Hydrothermal synthesis, Crystal structure, Tungstomolybdophosphate

CLC Number:

O614

TrendMD:

LIU Zong-Rui, WANG Li, CHEN Bao-Guo, XU Lin, WANG En-Bo, XING Yan, JIA Heng-Qing, LIN Yong-Hua. Hydrothermal Synthesis and Characterizaton of [CH₃NH₃][NH₃(CH₂)₆NH₃]H₃[P₂Mo₂W₁₆O₆₂]·H₂O[J]. Chem. J. Chinese Universities, 2003, 24(5): 772.

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Hydrothermal Synthesis and Characterizaton of [CH₃NH₃][NH₃(CH₂)₆NH₃]H₃[P₂Mo₂W₁₆O₆₂]·H₂O

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