Synthesis, Crystal Structure and Activity Study of 2D Polymeric Complex [MnNa(Salicylate)2(CH3OH)(H2O)]n·0.5nH2O

Abstract

Abstract: In this paper, a novel polymeric complex [MnNa(Salicylate)₂(CH₃OH)(H₂O)]_n·0.5nH₂O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is crystallized in triclinic system, space group P1 with a=0.763 82(15) nm, b= 1.037 1(2) nm, c=1.290 9(3) nm, α= 103.59(3)°, β=104.65(3)°, γ=109.50(3)°, V=0.873 6(3) nm³, Z=2, D_c=1.556 Mg/m³, M_r=409.20, μ=0.823 mm^-1, F(000)=418, R=0.0614, _wR= 0.147 6. The activity in catalyzing the superoxygen anionic free radical dismutation was determinated.

Key words: Manganese complex, Mn SOD, Crystal structure, Two-dimension polymeric complex

CLC Number:

O641

TrendMD:

SHI Wei, XU Ying-Kai, WANG Hong-Mei, LIU Yang  . Synthesis, Crystal Structure and Activity Study of 2D Polymeric Complex [MnNa(Salicylate)₂(CH₃OH)(H₂O)]_n·0.5nH₂O[J]. Chem. J. Chinese Universities, 2003, 24(3): 516.

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Synthesis, Crystal Structure and Activity Study of 2D Polymeric Complex [MnNa(Salicylate)₂(CH₃OH)(H₂O)]_n·0.5nH₂O

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