Hydrothermal Synthesis and Characterization of an Open Framework Zincophosphate with Zn4O4 Tetrameric Clusters

Abstract

Abstract: The organically templated single crystal of Zn₅(PO₄)₄·H₃N(CH₂)₄NH₃ was synthesized by hydrothermal method and its structure was determined by single-crystal X-ray diffraction. Crystal data: orthorhombic, space group Pnma with lattice parameters a=1.834 40(6) nm, b= 1.330 34(4)} nm, c={0^744 97(2)} nm, β=90°, V=1.818 01(9) nm³, Z=4, R₁=0.030 9, wR₂={0^080 4} . The framework is built up of a network of ZnO₄ and PO₄ tetrahedra. The Zn₄O₄ clusters in the compound are linked to PO₄ tetrahedra to form basket-shaped building units, which are connected to each other via oxygens, in an alternate up-down manner, to form the three-dimensional architecture.

Key words: Hydrothermal synthesis, Zincophosphate, Crystal structure, 1,4-Diaminobutane

CLC Number:

O614

TrendMD:

XING Yan, FU Yun-Long, SHI Zhan, HUA Jia, ZHANG Ping, CUI Yan-Jie, PANG Wen-Qin . Hydrothermal Synthesis and Characterization of an Open Framework Zincophosphate with Zn₄O₄ Tetrameric Clusters[J]. Chem. J. Chinese Universities, 2003, 24(3): 377.

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Hydrothermal Synthesis and Characterization of an Open Framework Zincophosphate with Zn₄O₄ Tetrameric Clusters

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