Hydrothermal Synthesis and Crystal Structure of a New Cage-like Isopolyoxovanadate [Ni(1,10′-phen)3]2 [V2ⅣV8ⅤO26]

Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (1): 34.

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Hydrothermal Synthesis and Crystal Structure of a New Cage-like Isopolyoxovanadate [Ni(1,10′-phen)₃]₂ [V₂^ⅣV₈^ⅤO₂₆]

LI Yang-Guang¹, LUAN Guo-You¹, WANG En-Bo¹, WANG Shu-Tao¹, HU Chang-Wen¹, HU Ning-Hai², JIA Heng-Qing²

1. Faculty of Chemistry, Northeast Normal University, Changchun 130024, China;
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2002-01-06 Online:2003-01-24 Published:2003-01-24

Abstract

Abstract: A new isopolyoxovanadate [Ni(1,10′-phen)₃]₂ [V^Ⅳ₂V^Ⅴ₈O₂₆] was hydrothermally synthesized and structurally characterized by the single crystal X-ray diffraction. The compound crystallizes in orthorhombic system, space group Pbcn with a=1.362 9(3) nm, b=2.215 6(4) nm, c= 2.571 2(4) nm, V=7.764(2) nm³, Z=4, R=0.040 3, wR₂=0.044 6. The compound exhibits an unusual empty ellipsoidal cage, which is constructed by eight {V^ⅤO₄} tetrahedra and two {V^ⅣO₅} square pyramids via corner-sharing modes. The chiral [Ni(1,10′-phen) 3]²⁺ complexes act as the counter cations.

Key words: Isopolyoxovanadate, Mixed valence, Hydrothermal synthesis, Crystal structure

CLC Number:

O611

TrendMD:

LI Yang-Guang, LUAN Guo-You, WANG En-Bo, WANG Shu-Tao, HU Chang-Wen, HU Ning-Hai, JIA Heng-Qing . Hydrothermal Synthesis and Crystal Structure of a New Cage-like Isopolyoxovanadate [Ni(1,10′-phen)₃]₂ [V₂^ⅣV₈^ⅤO₂₆][J]. Chem. J. Chinese Universities, 2003, 24(1): 34.

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Hydrothermal Synthesis and Crystal Structure of a New Cage-like Isopolyoxovanadate [Ni(1,10′-phen)₃]₂ [V₂^ⅣV₈^ⅤO₂₆]

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