A 3-D Inorganic-organic Hybrid Framework Microporous Material──Synthesis and Characteristic of [Co3(BTC)(HBTC)(H2BTC)(C2H4O2)3]·3(DMF)·6(H3O)

Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (1): 28.

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A 3-D Inorganic-organic Hybrid Framework Microporous Material──Synthesis and Characteristic of [Co₃(BTC)(HBTC)(H₂BTC)(C₂H₄O₂)₃]·3(DMF)·6(H₃O)

FANG Qian-Rong, SHI Xin, XIN Ming-Hong, WU Gang, TIAN Ge, ZHU Guang-Shan, LI Ya-Feng, YE Ling, WANG Chun-Lei, ZHANG Zhen-Dong, TANG Lu-Lu, QIU Shi-Lun

College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China

Received:2002-09-29 Online:2003-01-24 Published:2003-01-24

Abstract

Abstract: Compound [Co₃(BTC)(HBTC)(H₂BTC)(C₂H₄O₂) 3]·3(DMF)·6(H₃O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a=2.645 3(5) nm, b= 1.670 4(3) nm, c=1.821 6(4) nm, β=128.16(3) °, V=6.329(2) nm³, Z=2 , D_c=20.200 Mg/m³, M r= 1 314.744, μ=10.274 mm^-1, F(000) =38 226, GOF=0.99, R=0.094 1, ωR=0.257 3.

Key words: Crystal structure, Inorganic-organic hybrid framework, Microporous material

CLC Number:

O641

TrendMD:

FANG Qian-Rong, SHI Xin, XIN Ming-Hong, WU Gang, TIAN Ge, ZHU Guang-Shan, LI Ya-Feng, YE Ling, WANG Chun-Lei, ZHANG Zhen-Dong, TANG Lu-Lu, QIU Shi-Lun. A 3-D Inorganic-organic Hybrid Framework Microporous Material──Synthesis and Characteristic of [Co₃(BTC)(HBTC)(H₂BTC)(C₂H₄O₂)₃]·3(DMF)·6(H₃O)[J]. Chem. J. Chinese Universities, 2003, 24(1): 28.

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A 3-D Inorganic-organic Hybrid Framework Microporous Material──Synthesis and Characteristic of [Co₃(BTC)(HBTC)(H₂BTC)(C₂H₄O₂)₃]·3(DMF)·6(H₃O)

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