Selective Hydrogenation of Acetic Acid to Acetaldehyde over SBA-15 Supported Iron Oxide Catalysts

Abstract

Abstract: A series of SBA-15 supported α-Fe₂O₃ catalysts were prepared and characterized. The influence of iron oxide loading, reduction temperature and reaction temperature on the catalytic activity and selectivity for the selective hydrogenation of acetic acid to acetaldehyde was investigated. The highest yield of acetaldehyde over the supported catalysts is 42.7%, whereas that over non-supported α-Fe₂O₃ is only 32.2%. The hydrogenation catalysts need to be prereduced before reaction. The optinum reduction temperatures for α-Fe₂O₃ and the supported catalyst are 873 and 923 K, respectively. The selective hydrogenation to acetaldehyde is favored when Fe₃O₄ and Fe⁰ coexist on the catalyst surface, and acetaldehyde is likely formed via a Mars-van Krevelen reaction mechanism.

Key words: Iron oxide, SBA-15 molecular sieve, Selective hydrogenation, Acetic acid, Acetaldehyde

CLC Number:

O643.1

TrendMD:

ZHANG Xue-Zheng, YUE Ying-Hong, GAO Zi. Selective Hydrogenation of Acetic Acid to Acetaldehyde over SBA-15 Supported Iron Oxide Catalysts[J]. Chem. J. Chinese Universities, 2003, 24(1): 121.

[1]	SONG Youwei, AN Jiangwei, WANG Zheng, WANG Xuhui, QUAN Yanhong, REN Jun, ZHAO Jinxian. Effects of Ag，Zn，Pd-doping on Catalytic Performance of Copper Catalyst for Selective Hydrogenation of Dimethyl Oxalate [J]. Chem. J. Chinese Universities, 2022, 43(6): 20210842.
[2]	LI Xueyu, WANG Zhao, CHEN Ya, LI Keke, LI Jianquan, JIN Shunjing, CHEN Lihua, SU Baolian. Enhanced Catalytic Performance of Supported Nano-gold by the Localized Surface Plasmon Resonance for Selective Hydrogenation of Butadiene [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220174.
[3]	ZHONG Shengguang, XIA Wensheng, ZHANG Qinghong, WAN Huilin. Theoretical Study on Direct Conversion of CH₄ and CO₂ into Acetic Acid over MCu₂O_x（M = Cu²⁺， Ce⁴⁺， Zr⁴⁺） Clusters [J]. Chem. J. Chinese Universities, 2021, 42(9): 2878.
[4]	HE Xiaoke, LI Xiaoyun, WANG Zhao, HU Nian, DENG Zhao, CHEN Lihua, SU Baolian. Self-reduction for the Synthesis of Co Supported on Hierarchically Porous Carbon for Selective Hydrogenation Reaction ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 639.
[5]	WANG Xiaoqun, HUANG Guangming. Investigation of Lipid Distributions by Trifluoroacetic Acid-enhanced Desorption Electrospray Ionization Mass Spectrometry Imaging [J]. Chem. J. Chinese Universities, 2020, 41(12): 2673.
[6]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[7]	DONG Deming,ZHANG Ying,HUA Xiuyi,JIANG Xu,LIANG Dapeng,GUO Zhiyong. Effect of Dissolved Organic Matter on the Generation of H₂O₂ in Natural Biofilm Systems Under Illumination^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 800.
[8]	PAN Shuai, HU Xiaobing, SONG Runmin, XIE Lili, ZHU Zhigang, ZHENG Liaoying. Ionic Liquid Assisted Synthesis of α-Fe₂O₃ Nanospheres Based on Potassium Acetate Solution and Their Gas-sensing Properties^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1631.
[9]	JIANG Xue,FU Yao,HUANG Dan,GUO Yupeng. Colour Change of Red Iron Oxide by One-step Method Using Oxidant^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2734.
[10]	A Shan, ZHEN Jiawei, LIU Juming, BAI Jie, YANG Jucai, ZHANG Qiancheng. Preparation and Synergistic Catalytic Performance of Ag/TiO₂ Composite Photocatalysts Modified by Acetic Acid [J]. Chem. J. Chinese Universities, 2017, 38(8): 1450.
[11]	HAN Yanmei, GAO Zhihua, HUANG Wei. Effects of AlOOH Structure on the Reaction of Methanol and Carbon Monoxide^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 823.
[12]	CAO Yongyong, JIANG Junhui, NI Zheming, XIA Shengjie, QIAN Mengdan, XUE Jilong. Cluster Properties of Au₁₉Pt and Selective Hydrogenation Mechanism of Cinnamaldehyde on Au₁₉Pt Cluster Surface^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1342.
[13]	JIANG Junhui, XIA Shengjie, NI Zheming, Zhang Lianyang. Adsorption and Selective Hydrogenation Mechanism of Crotonaldehyde on AuSurface [J]. Chem. J. Chinese Universities, 2016, 37(4): 693.
[14]	HU Qi, FANG Chao, ZHAO Wai’ou, LI Yapeng, CHEN Xia, WANG Jingyuan. Synthetic of PGMA-EDA-g-PEG-g-DS@IO as a Magnetic Resonance Contrast Agent for Atherosclerosis^† [J]. Chem. J. Chinese Universities, 2015, 36(10): 2061.
[15]	SUN Haijie, CHEN Lingxia, HUANG Zhenxu, LIU Shouchang, LIU Zhongyi. Particle Size Effect of Ru-Zn Catalysts on Selective Hydrogenation of Benzene to Cyclohexene^† [J]. Chem. J. Chinese Universities, 2015, 36(10): 1969.

Selective Hydrogenation of Acetic Acid to Acetaldehyde over SBA-15 Supported Iron Oxide Catalysts

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments