Hydrothermal Synthesis and Characterization of a New Compound [Ni(en)3]2[Ni(en)2(H2O)2]·[As6V15O42]·4H2O

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (9): 1670.

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Hydrothermal Synthesis and Characterization of a New Compound [Ni(en)₃]₂[Ni(en)₂(H₂O)₂]·[As₆V₁₅O₄₂]·4H₂O

LUAN Guo-You^1,3, WANG Ming-Hui³, HAN Zheng-Bo¹, WANG En-Bo¹, LU Ying¹, LI Yang-Guang¹, HU Chang-Wen¹, HU Ning-Hai², JIA Heng-Qing²

1. Department of Chemistry, Northeast Normal University, Changchun 130024, China;
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
3. College of Resource and Enviroment, Jilin Agriculture University, Changchun 130118, China

Received:2001-06-08 Online:2002-09-24 Published:2002-09-24

Abstract

Abstract: Anew compound, [Ni(en)₃]₂[Ni(en)₂(H₂O)₂][As₆V₁₅O₄₂]·4H₂O, was first prepared by hydrothermal synthesis and characterized by elemental analysis, IR, TGA-DSC, ESRand single crystal X-ray diffraction. Crystal data: monoclinic, space group C_c, a=1.5236(3) nm, b=2.0518(4) nm, c=2.3959(5) nm, β=97.41(3)°, V=7.427(3) nm³, Z=4, R=0.0570, wR₂=0.1357. The polyanion consists of six AsO₃ pyramids and fifteen VO₅ pyramids. Counterions are complexions with octahedral structure, which consist of NH₂CH₂CH₂NH₂ and Ni+²⁺.

Key words: Polyoxometalate, Hydrothermal synthesis, Crystal structure

CLC Number:

O611

TrendMD:

LUAN Guo-You, WANG Ming-Hui, HAN Zheng-Bo, WANG En-Bo, LU Ying, LI Yang-Guang, HU Chang-Wen, HU Ning-Hai, JIA Heng-Qing . Hydrothermal Synthesis and Characterization of a New Compound [Ni(en)₃]₂[Ni(en)₂(H₂O)₂]·[As₆V₁₅O₄₂]·4H₂O[J]. Chem. J. Chinese Universities, 2002, 23(9): 1670.

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Hydrothermal Synthesis and Characterization of a New Compound [Ni(en)₃]₂[Ni(en)₂(H₂O)₂]·[As₆V₁₅O₄₂]·4H₂O

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