Synthesis, Crystal Structure and Anti-prostate Cancer Activity of a Novel Organic-inorganic Hybrid Material:(C3H5N2)4PMoⅤMo11ⅥO40·4DMF·2H2O

Abstract

Abstract: Anew compound, (C₃H₅N₂)₄PMo^ⅤMo₁₁^ⅥO₄₀)·4C₃H₇NO·2H₂O, was synthesized and structurally characterized by elemental analysis, ESRspectra and X-ray diffraction. This is the first example of imidazole-polyoxometalate species to our knowledge. It crystallized in a triclinic space group, P1 with a=1.2423(3) nm, b=1.2666(3) nm, c=1.3341(3) nm, V=1.7423(6) nm³, α=70.56(3)°, β=71.16(3)°, γ=64.18(3)°, Z=1, R=0.0585, wR=0.1885. X-ray crystallographic study showed that the crystal structure was constructed by electrostatic attractions and hydrogen bonds between a dodecamolybdophosphoric anion and an imidazole. Anti-prostate cancer(PC-3m) activities of the title compound are also reported.

Key words: Organic-inorganic hybrid material, Polyoxometalate, Imidazole, Crystal structure, Anti-prostate cancer activities

CLC Number:

O611

TrendMD:

HAN Zheng-Bo, CHANG Ya-Ping, LUAN Guo-You, LI Juan, WANG En-Bo. Synthesis, Crystal Structure and Anti-prostate Cancer Activity of a Novel Organic-inorganic Hybrid Material:(C₃H₅N₂)₄PMo^ⅤMo₁₁^ⅥO₄₀·4DMF·2H₂O[J]. Chem. J. Chinese Universities, 2002, 23(9): 1660.

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Synthesis, Crystal Structure and Anti-prostate Cancer Activity of a Novel Organic-inorganic Hybrid Material:(C₃H₅N₂)₄PMo^ⅤMo₁₁^ⅥO₄₀·4DMF·2H₂O

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