Hydrothermal Synthesis and Characterization of Ni3(PO4)2·8H2O with8-Ring and4-Ring Network Structure

Abstract

Abstract: Anew two dimensional 8-ring network nickle phosphate Ni₃(PO₄)₂·8H₂Owas synthesized hydrothermally and its structure was determined by means of single-crystal X-ray diffraction. The Ni₃(PO₄)₂·8H₂Ocrystal crystallizes in the monoclinic system, space group C₂/m, with M=128.13, a=0.9947(2) nm, b=1.3217(3)nm; c=0.4636(1) nm; β=104.80(3)°, V=0.5893(2) nm³, Z=2, R=0.0272 and wR=0.0575. The network structure consists of vertex sharing which results in the formation of undulating 4-ring chains and 8-ring sheets.

Key words: Hydrothermal synthesis, Crystal, Structure

CLC Number:

O641

TrendMD:

LI Ya-Feng, CUI Wei, ZHU Guang-Shan, QIU Shi-Lun, FANG Qian-Rong, WANG Chun-Lei . Hydrothermal Synthesis and Characterization of Ni₃(PO₄)₂·8H₂O with₈-Ring and₄-Ring Network Structure[J]. Chem. J. Chinese Universities, 2002, 23(8): 1480.

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Hydrothermal Synthesis and Characterization of Ni₃(PO₄)₂·8H₂O with₈-Ring and₄-Ring Network Structure

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