Synthesis and Properties of [2-(2-Hydroxyphenyl)iminomethyl- [JZ]benzenethiolato(2-)-N,O,S](2-methoxy-(2-methoxy-carbonylethyl-C,O)tin Chloride

Abstract

Abstract: The title complex, [2-(2-hydroxyphenyl)iminomethyl benzenethiolato(2-)-N, O, S] (2-methoxycarbonylethyl-C, O) tin chloride, CH₃OCOCH₂CH₂SnClL(L=2-SC₆H₄CHN⁼C₆H₄O₂), was synthesized by the reaction of 2 methoxycarbonylethyltin trichloride with N (2 hydroxy phenyl)thiosalicylideneimine. This complex reacted with neutral monodentate ligands such as dimethylsulfoxide(DMSO) and hexamethylphosphoramide(HMPA) to form the mixed ligand complexes, CH₃OCOCH₂CH₂SnClLL′(L′=DMSO, HMPA), and also readily underwent transesterification with alcohols to produce the corresponding₂alkoxycarbonylethyltin analogues, ROCOCH₂CH₂SnClL. These complexes were characterized by means of elemental analysis, IRand ¹H NMRspectra. The crystal structure for the title complex was determined by X-ray diffraction analysis. The crystal belongs to triclinic system, space group P₁with cell parameters α=0.8704(2) nm, b=0.9393(3) nm, c=1.4511(3) nm, α=98.05(3)°, β=103.03(3)°, γ=6.99(3)°, V=1.1299(4) nm³, Z=2, D_c=1.378 g/cm³, F (000)=524. In this compound, the tin atom adopts a distorted octahedral geometry via intramolecular carbonyl oxygen atom and the sulfur, nitrogen and oxygen atoms of the chelating ligand Lto tin coordination.

Key words: Tin(Ⅳ) complex, N (2 Hydroxyphenyl)thiosalicylideneimine, 2 Methoxycarbonylethyltin trichloride, Crystal structure

CLC Number:

O614.12

TrendMD:

TIAN Lai-Jin, ZHOU Zheng-Yu. Synthesis and Properties of [2-(2-Hydroxyphenyl)iminomethyl- [JZ]benzenethiolato(2-)-N,O,S](2-methoxy-(2-methoxy-carbonylethyl-C,O)tin Chloride[J]. Chem. J. Chinese Universities, 2002, 23(7): 1231.

References

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