Synthesis of 2-(p-Propenoyloxyphenyl)-5,10,15,20- tetraphenylporphyrin Nickel Polymer

Abstract

Abstract: 2-(p-propenoyloxyphenyl)-5,10,15,20-tetraphenylporphyrin nickel(Ⅱ) and 2-(o-propenoy-loxyphenyl)-5,10,15,20-tetraphenylporphyrin nickel(Ⅱ′) was synthesized from acryoyl chloride with 2 (p hydroxyphenyl)₅,10,15,20 tetraphenylporphyrin nickel(Ⅰ) and 2-(o-hydroxyphenyl)-5,10,15,20-tetraphenylporphyrin nickel(Ⅰ′) correspondingly. Compound (Ⅱ) was further polymerized to 2-(p-propenoyloxyphenyl)-5,10,15,20-tetraphenylporphyrin nickel(Ⅲ) in the presence of initiator. Their chemical structures were identified by NMR, UV-Vis, IR and MS spectra, as well as elemental analysis.

Key words: Synthesis, Porphyrin, Monomer, Polymer

CLC Number:

O614

TrendMD:

LI Ping-Ying, HUANG Qi-Mao, CHEN Zhang-Ping, MA Shu-Yi, Xu Han-Sheng. Synthesis of 2-(p-Propenoyloxyphenyl)-5,10,15,20- tetraphenylporphyrin Nickel Polymer[J]. Chem. J. Chinese Universities, 2002, 23(2): 173.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	TENG Zhenyuan, ZHANG Qitao, SU Chenliang. Charge Separation and Surface Reaction Mechanisms for Polymeric Single-atom Photocatalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220325.
[3]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[4]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[5]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[6]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[7]	WENG Meiqi, SHANG Guiming, WANG Jiatai, LI Shenghua, FAN Zhi, LIN Song, GUO Minjie. Template Simulation of Organophosphorus Nerve Agent Molecularly Imprinted Polymers [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220136.
[8]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[9]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[10]	WANG Zhengwen, GAO Fengxiang, CAO Han, LIU Shunjie, WANG Xianhong, WANG Fosong. Synthesis and Property of CO₂ Copolymer⁃based UV-curable Polymer [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220236.
[11]	DING Yang, WANG Wanhui, BAO Ming. Recent Progress in Porous Framework-immobilized Molecular Catalysts for CO₂Hydrogenation to Formic Acid [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220309.
[12]	QIU Liqi, YAO Xiangyang, HE Liangnian. Visible-light-driven Selective Reduction of Carbon Dioxide Catalyzed by Earth-abundant Metalloporphyrin Complexes [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220064.
[13]	JI Fa, LIU Ling, YU Linling, SUN Yan. Effects of Muco-inert and Acid-sensitive Modification on Mucosal Penetration of Nanoparticles [J]. Chem. J. Chinese Universities, 2022, 43(6): 20210837.
[14]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[15]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.

Synthesis of 2-(p-Propenoyloxyphenyl)-5,10,15,20- tetraphenylporphyrin Nickel Polymer

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments