Synthesis and Structure of a Novel Inorganic-organic Hybrid Framework Microporous Material Cd3（BDC）0.5（BTC）2（DMF）（H2O）·3DMF·H3O·H2O

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (11): 2040.

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Synthesis and Structure of a Novel Inorganic-organic Hybrid Framework Microporous Material Cd₃（BDC）_0.5（BTC）₂（DMF）（H₂O）·3DMF·H₃O·H₂O

SHI Xin, FANG Qian-Rong, XIN Ming-Hong, WU Gang, TIAN Ge, ZHU Guang-Shan, LI Ya-Feng, WANG Li-Feng, WANG Chun-Lei, SHANG Tie-Cun, QIU Shi-Lun

College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China

Received:2002-08-02 Online:2002-11-24 Published:2002-11-24

Abstract

Abstract: A new inorganic-organic hybrid framework microporous material Cd₃(BDC)_0.5(BTC)₂·(DMF)(H₂O)·3DMF·H₃O·H₂O, in which two kinds of carboxylate ligands coordinate with cadmium ions synchronously, was obtained under a mild synthesis condition. The titled compound is crystallized in a monoclinic system, space group P2(1)/c with a=1.584 7(7) nm, b=1.426 7(6) nm, c=1.936 3(6) nm, β=113.186(7)°, V=4.024 6(3) nm³, Z=4, D X=1.947 mg/m³, M r=1 179.92, μ=1.662 mm^-1, F(000)=2 344, R=0.074 8, wR=0.215 1. Three cadmium centers link with each other through BDC or BTC ligand to form a 3-D open framework.

Key words: Inorganic-organic hybrid frameworks, Microporous material, Crystal structure

CLC Number:

O641

TrendMD:

SHI Xin, FANG Qian-Rong, XIN Ming-Hong, WU Gang, TIAN Ge, ZHU Guang-Shan, LI Ya-Feng, WANG Li-Feng, WANG Chun-Lei, SHANG Tie-Cun, QIU Shi-Lun . Synthesis and Structure of a Novel Inorganic-organic Hybrid Framework Microporous Material Cd₃（BDC）_0.5（BTC）₂（DMF）（H₂O）·3DMF·H₃O·H₂O[J]. Chem. J. Chinese Universities, 2002, 23(11): 2040.

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Synthesis and Structure of a Novel Inorganic-organic Hybrid Framework Microporous Material Cd₃（BDC）_0.5（BTC）₂（DMF）（H₂O）·3DMF·H₃O·H₂O

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