Synthesis and Properties of Highly Soluble Polyimide Containing Perylene Units

Abstract

Abstract: A series of high molecular weight copolyimides containing various amounts of perylene units in the main-chain were synthesized. The products were characterized by FTIR, NMR, UV-Vis, fluorescence spectroscopy, GPC, DSC and TGA measurements. They are highly soluble in conventional solvents such as chloroform, THF, cyclohexanone etc. and form optically transparent films by solution casting or spin-coating. The copolyimide containing 0.5%(molar fraction) perylene units exhibits the highest solid-state fluorescence. The polyimides are thermally stable up to 400 ℃ and exhibit glass transition temperatures in the range of 340～360 ℃. The number-average molecule weight ranges from 1.72×10⁴ to 1.25×10⁵ and the molecule weight distribution mediated between 1.9 to 2.4.

Key words: Perylene, Polyimides, Solubility, Fluorescence

CLC Number:

O631

TrendMD:

HUANG Wei, YAN De-Yue, LU Qing-Hua . Synthesis and Properties of Highly Soluble Polyimide Containing Perylene Units[J]. Chem. J. Chinese Universities, 2002, 23(10): 2005.

[1]	WANG Junyang, LIU Zheng, ZHANG Qian, SUN Chunyan, LI Hongxia. Application of DNA Silver Nanoclusters in the Fluorescence Biosensors based on Functional Nucleic Acids [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220010.
[2]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[3]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[4]	LI Qiao, ZHAO Yang, WANG Enju. Moisture Absorption Reaction and Fluorescence Property of Highly Active Michael System Based on Arylidenemalononitrile [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210690.
[5]	TIAN Xueqin, MO Zheng, DING Xin, WU Pengyan, WANG Yu, WANG Jian. A Squaramide-containing Luminescent Metal-organic Framework as a High Selective Sensor for Histidine [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210589.
[6]	WU Zexin, ZHU Yuanjie, WANG Hongzhong, WANG Junan, HE Ying. Methyl-modified Carbazole/Diphenyl Sulfone-based AIE-TADF Blue Emitter and Its OLEDs [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220371.
[7]	LIU Miao, LIU Ruibo, LIU Badi, QIAN Ying. Synthesis， Two-photon Fluorescence Imaging and Photodynamic Therapy of Lysosome-targeted Indole-BODIPY Photosensitizer [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220326.
[8]	HAN Zongsu, YU Xiaoyong, MIN Hui, SHI Wei, CHENG Peng. A Rare Earth Metal-Organic Framework with H₆TTAB Ligand [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210342.
[9]	MA Jianxin, LIU Xiaodong, XU Na, LIU Guocheng, WANG Xiuli. A Multi-functional Zn（II） Coordination Polymer with Luminescence Sensing， Amperometric Sensing， and Dye Adsorption Performance [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210585.
[10]	WU Ji, ZHANG Hao, LUO Yuhui, GENG Wuyue, LAN Yaqian. A Microporous Cationic Ga（III）-MOF with Fluorescence Properties for Selective sensing Fe³⁺ Ion and Nitroaromatic Compounds [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210617.
[11]	LI Ran, ZHANG Xudong, MU Lidan, SUN Tong, AI Ganggang, SHA Yelong, ZHANG Yuqi, WANG Jijiang. Preparation and Application of Triplethiophene Derivative Functionalized SiO₂ Inverse Opal Photonic Crystal Fluorescent Films [J]. Chem. J. Chinese Universities, 2021, 42(9): 2989.
[12]	WANG Shoubai, WU Xiuming, WU Jinming, TANG Yanfeng, SHU Chen, ZHONG Min, HUANG Wei, YAN Deyue. Synthesis and Properties of Soluble Transparent Polyimides Containing tert-Butyl and Isobutyl Groups [J]. Chem. J. Chinese Universities, 2021, 42(9): 2944.
[13]	YUAN Chunling, YAO Xiaotiao, XU Yuanjin, QIN Xiu, SHI Rui, CHENG Shiqi, WANG Yilin. Colorimetry/Ratio Fluorimetry Determination of Glucose with Bifunctional Carbon Dots [J]. Chem. J. Chinese Universities, 2021, 42(8): 2428.
[14]	ZHOU Jieqiong, HUANG Yan, ZHANG Zhiling, PANG Daiwen, TIAN Zhiquan. Water-soluble Ag₂Te Quantum Dots with Emission in the Second Near-infrared Window [J]. Chem. J. Chinese Universities, 2021, 42(6): 2072.
[15]	WANG Xianwei, KE Hongjun, YUAN Hang, LU Gewu, LI Liying, MENG Xiangsheng, SONG Shulin, WANG Zhen. High Temperature Resistant and Soluble Polyimide Resins and Their Composites [J]. Chem. J. Chinese Universities, 2021, 42(6): 2041.

Synthesis and Properties of Highly Soluble Polyimide Containing Perylene Units

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments