Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)3]4[Mo5ⅤMo5ⅥV6ⅣO40(PO4)]2·4H2O Containing Double Tetracapped Pseudo-Keggin Cluster Anions

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (10): 1854.

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Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)₃]₄[Mo₅^ⅤMo₅^ⅥV₆^ⅣO₄₀(PO₄)]₂·4H₂O Containing Double Tetracapped Pseudo-Keggin Cluster Anions

ZENG Qing-Xin¹, LÜ Gao-Meng³, LI Ya-Feng², YANG Guo-Yu¹, XU Ji-Qing²

1. Coordination and Hydrothermal Chemistry Group, State Key Laboratory of the Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2. College of Chemistry, Jilin University, Changchun 130023, China;
3. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Received:2001-12-31 Online:2002-10-24 Published:2002-10-24

Abstract

Abstract: The title compound[Co(2,2-bipy)₃]₄[Mo₁₀V₆O₄₀(PO₄)]₂·4H₂O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a=316 5(3)nm, b=1.438 2(3) nm, c=2.764 4(6) nm, α=79.51°, β=89.95°, γ=68.89°, V=4.789 3(17)nm³, Z=1, D_c=2.176 g/cm³, R=0.075 5, wR=0.205 3, S=0.995.

Key words: Hydrothermal synthesis, Pseudo-Keggin, Crystal structure

CLC Number:

O614

TrendMD:

ZENG Qing-Xin, LÜ Gao-Meng, LI Ya-Feng, YANG Guo-Yu, XU Ji-Qing . Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)₃]₄[Mo₅^ⅤMo₅^ⅥV₆^ⅣO₄₀(PO₄)]₂·4H₂O Containing Double Tetracapped Pseudo-Keggin Cluster Anions[J]. Chem. J. Chinese Universities, 2002, 23(10): 1854.

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Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)₃]₄[Mo₅^ⅤMo₅^ⅥV₆^ⅣO₄₀(PO₄)]₂·4H₂O Containing Double Tetracapped Pseudo-Keggin Cluster Anions

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