Structure and Properties of Dibridged (μ-oxo)(μ-CO3) diiron(Ⅲ) Complex

Abstract

Abstract: A ( μ oxo)( μ-CO₃)diiron(Ⅲ) complex of tri(2-pyridylmethyl)amine(TPA), [Fe₂L₂( μ-O) ( μ-CO₃)] (ClO₄)₂·MeOH·EtOH·H₂O], was synthesized and characterized, where Lrepresents TPA. This complex crystallizes in the monoclinic space group P2₁/c with a=1.1810(3)_nm, b=3.7281(8)_nm, c=1.3770(3)_nm , β=115.393(3)°, V=5.477(2)_nm³, Z=4. R₁=0.0849 and wR₂=0.1962. The UV-Vis spectra of this compound show multiply absorption bands in₂₀₀-800 nm range, which are similar to that of N₃^- coordinated met hemerythrin. , was synthesized and characterized, where Lrepresents TPA. This complex crystallizes in the monoclinic space group P2₁/c with a=1.1810(3)_nm, b=3.7281(8)_nm, c=1.3770(3)_nm , β=115.393(3)°, V=5.477(2)_nm³, Z=4. R₁=0.0849 and wR₂=0.1962. The UV Vis spectra of this compound show multiply absorption bands in 200-800 nm range, which are similar to that of N₃^- coordinated met hemerythrin.

Key words: Diiron complex, μ-oxo-complex, Crystal structure

CLC Number:

O641.4

TrendMD:

YAN Shi-Ping, WANG Qing-Lun, CHENG Peng, LIU Xin, LIAO Dai-Zheng JIANG Zong-Hui, LENG Xue-Bing, WENG Lin-Hong . Structure and Properties of Dibridged (μ-oxo)(μ-CO₃) diiron(Ⅲ) Complex[J]. Chem. J. Chinese Universities, 2001, 22(8): 1292.

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Structure and Properties of Dibridged (μ-oxo)(μ-CO₃) diiron(Ⅲ) Complex

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