Synthesis and GC Properties of Heptakis(2,6-di-O-pentyl-3-O-benzyl)-β-cyclodextrin

Abstract

Abstract: A β-cyclodextrin derivative, heptakis(2,6-di-O-pentyl-3-O-benzyl)-β-CD, was synthesized and used as GCstationary phase. The chromatographic results show that the CDs is a good GCstationary phase with a good film forming property, moderate polarity and good separation ability to disubstituted benzene isomers such as cresols and xylene isomers. The chromatographic properties of heptakis(2,6-di-O-pentyl-3-O-benzyl)-β-CDare better than OV-225 because of the peculiar cavity of β-cyclodextrin.

Key words: Capillary gas chromatography, Stationary phase, Cyclodextrin derivatives

CLC Number:

O658

TrendMD:

SHI Xue-Yan, SHAO Qing-Long, TAO Dan-Ni, GU Jun-Ling, FU Ruo-Nong  . Synthesis and GC Properties of Heptakis(2,6-di-O-pentyl-3-O-benzyl)-β-cyclodextrin[J]. Chem. J. Chinese Universities, 2001, 22(7): 1098.

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Synthesis and GC Properties of Heptakis(2,6-di-O-pentyl-3-O-benzyl)-β-cyclodextrin

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