Interaction Parameters of the Excess Gibbs Free Energy Between Saccharides and Non-electrolytes in Formamide

Abstract

Abstract: The retention values of ten non-electroltyes in stationary solution of formamide-glucose, formamide-fructose and formamide-sucrose at 298.15 Kwere measured by a gas-liquid chromatographic method(GLC). Depending on the McMillan-Mayer theory, the values of pair and triplet interaction parameters g_ij andg_ijj of saccharides with non-electroltyes have been evaluted. The group interaction Gibbs free energy parametersG_x,y were evaluted by the Okamoto-Wood group additivity method. The information about the solute-solute interaction and the effect of solvent were discussed.

Key words: Gibbs energy interaction parameter, Group additivity, Gas-liquid chromatographic method, Saccharide, Non-electrolyte, Formamide

CLC Number:

O645.16

TrendMD:

TANG Qing-Hu, BAI Tong-Chun, LU Yan, ZHAO Pei-Zhen, LU Jin-Suo . Interaction Parameters of the Excess Gibbs Free Energy Between Saccharides and Non-electrolytes in Formamide[J]. Chem. J. Chinese Universities, 2001, 22(2): 240.

[1]	ZHU Kai, LI Jie, WU Xiaoyi, HU Weiwei, WU Dongmei, YU Chengxiao, GE Zhiwei, YE Xingqian, CHEN Shiguo. Combined PGC-Triple-Tof-MS Enables the Separation， Identification of Sugar Beet Pectin Derived Oligomers [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220023.
[2]	LI Lei, FANG Yun, XIA Yongmei, BO Chunling, FAN Ye. Comparative Effects of Mono/disaccharides on Conjugated Linoleic Acid Vesicles at Near Neutral pH [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210860.
[3]	HU Haocheng, LI Wenli, ZHANG Jianing, LIU Yubo. Extraction， Structure Characterization and Biological Activities of Oligosaccharides from Auricularia heimuer [J]. Chem. J. Chinese Universities, 2021, 42(8): 2465.
[4]	HOU Hua, WANG Baoshan. Group Additivity Theoretical Model for the Prediction of Dielectric Strengths of the Alternative Gases to SF₆ [J]. Chem. J. Chinese Universities, 2021, 42(12): 3709.
[5]	BAO Han, LUO Jing, SHI Lianxin, XU Fujian, WANG Shutao. Fabricating Polysaccharide Micro-hydrogel via Superhydrophobic Pillar-structured Si Substrate ^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1484.
[6]	WANG Tingting, LI Yuan, YANG Lili, BAO Changhao, CHENG Han. In vivo Dynamic Detection of Aloe Polysaccharides Using Carbon Fiber Microelectrodes Modified with Gold Nanoparticles ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 87.
[7]	JIN Xin,JI Guoli,ZHAO Xiaoliang,LI Guoyun,YU Guangli. Sulfated Arabinose from Codium fragile: Preparation and Extensive Structural Characterization^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 733.
[8]	YANG Mingming,NAN Lijing,JIN Wanjun,WANG Chengjian,HUANG Linjuan,ZHANG Ying,WANG Zhongfu. Quali-quantitative Profiling of Mucin-type O-Glycans in Normal and Tumor Cell Lines Based on Oligosaccharide Metabolic Engineering Combined with Mass Spectrometry^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1904.
[9]	LING Yao, LIU Xuejing, HAO Haijing, HAO Xiaohui, BAI Libin, WU Yonggang. Synthesis and Properties of Water-soluble Glycosyl Fluorescent Polymer with Aggregation-induced Emission Effect^† [J]. Chem. J. Chinese Universities, 2018, 39(6): 1319.
[10]	GAO Yunxiao,HU Xiaolong,WANG Yuerong,JIANG Zhihong,ZHANG Hongyang,ZHANG Min,HU Ping. Primary Structural Analysis of Dendrobium officinale Polysaccharide^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 934.
[11]	LANG Yinzhi, LIU Shilong, WANG Chen, ZHANG Xiao, LÜ Youjing, CAI Chao, LI Guoyun, YU Guangli. Separation and Structural Sequence Analysis of Sialylated HMOs via Tandem Mass Spectrometry^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 645.
[12]	GENG Lihua, JIN Weihua, WANG Jing, ZHANG Quanbin. Fucoidan Degradation and Preparation of Fuco-oligosaccharides from Saccharina japonica^† [J]. Chem. J. Chinese Universities, 2017, 38(12): 2193.
[13]	ZHAO Qi, HE Wanying, DUAN Lijie, ZHANG Yu, YU Shuangjiang, GAO Guanghui. Fabrication and Characterization of Injectable Polysaccharide-polypeptide Hydrogel Based on Schiff’s Base^† [J]. Chem. J. Chinese Universities, 2016, 37(9): 1750.
[14]	ZHANG Xiao, SHAN Xindi, ZHAO Xiaoliang, LI Guoyun, WANG Xiaojiang, CAI Chao, HAO Jiejie, YU Guangli. Preparation, Characterization and Immunological Activity Evaluation of Low Anticoagulant Heparin Oligosaccharides^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1335.
[15]	SHEN Yanhong, CHEN Linxiao, ZHANG Wenqing, XU Zhizhen, WAN Yanfei, ZHANG Li, XIA Wei. Structural Characterization of Mannatide^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1088.

Interaction Parameters of the Excess Gibbs Free Energy Between Saccharides and Non-electrolytes in Formamide

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments