Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)2(H2O)2] 2· [Mo4Ⅴ Mo4ⅥV8ⅣO40 (AsO4)] Containing Different Coordinated Cations

Abstract

Abstract: The title compound [Co(en)₂(H₂O)₂] 2· [Mo⁴^Ⅴ Mo⁴^Ⅵ V⁸^Ⅳ O₄₀ (AsO₄)] was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a tetracapped Keggin polyanion, which contains different coordinated cations. The crystal is monoclinic, space group C2/c with a=1.4583(2) nm, b=2.17407(13) nm, c=1.8932(2) nm, β=91.532°, V=6.0002(10) nm³, Z=2, D_c=1.452 g/cm³, R=0.0359, Rw=0.0798, S=1.092.

Key words: Hydrothermal synthesis, Tetracapped Keggin structure, Crystal structure

CLC Number:

O614

TrendMD:

ZENG Qing-Xin, XU Ji-Qing, YANG Guo-Yu, LI Ya-Feng, CUI Xiao-Bing, ZHAO Xiao-Li, LI Chuan-Bi . Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)₂(H₂O)₂] ₂· [Mo₄^Ⅴ Mo₄^ⅥV₈^ⅣO₄₀ (AsO₄)] Containing Different Coordinated Cations[J]. Chem. J. Chinese Universities, 2001, 22(11): 1800.

[1]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[2]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[3]	LIANG Yu, LIU Huan, GONG Lige, WANG Chunxiao, WANG Chunmei, YU Kai, ZHOU Baibin. Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW₁₂O₄₀｝ Hybrid [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210556.
[4]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[5]	ZHANG Huishuang, GAO Yanxiao, WANG Qiuxian, LI Xiangnan, LIU Wenfeng, YANG Shuting. High-low Temperature Properties of Ni-rich LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Material by Hydrothermal Synthesis with CTAB Assisted [J]. Chem. J. Chinese Universities, 2021, 42(3): 819.
[6]	WANG Ye, ZHANG Xiaosi, SUN Lijing, LI Bing, LIU Lin, YANG Miao, TIAN Peng, LIU Zhongyi, LIU Zhongmin. Morphology Control of SAPO Molecular Sieves under the Assistance of Organosilane [J]. Chem. J. Chinese Universities, 2021, 42(3): 683.
[7]	WANG Jianyu, ZHANG Qiang, YAN Wenfu, YU Jihong. Roles of Hydroxyl Radicals in Zeolite Synthesis [J]. Chem. J. Chinese Universities, 2021, 42(1): 11.
[8]	WU Qinming, WANG Yeqing, MENG Xiangju, XIAO Fengshou. Reconsideration of Crystallization Process for Aluminosilicate Zeolites [J]. Chem. J. Chinese Universities, 2021, 42(1): 21.
[9]	LIU Yabing,LI Mingyang,TIAN Ge,ALATENG Shaga,PEI Tonghe,NIE Jingsi. Syntheses, Structures and Catalytic Properties of Two Supramolecular Complexes Based on 2-Pyridylamine and Cluster ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 995.
[10]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[11]	ZHUO Mengning,LI Fei,JIANG Hao,CHEN Qianwen,LI Peng,WANG Lizhang. Preparation of SnO₂/GDE Cathodes and Their Electrocatalytic Reduction of CO₂ to Produce Formic Acid ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 530.
[12]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[13]	DONG Le, HUANG Xingliang, REN Junjie, DAI Xiaoping, LIU Zongyan, TIAN Hongfeng, WANG Zhidong, WU Xiaotong. Influence Mechanism of Particle Size and Distribution of Silica Sol in the Synthesis of Ferrierite Zeolite with High SiO₂/Al₂O₃ Ratio [J]. Chem. J. Chinese Universities, 2020, 41(11): 2449.
[14]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[15]	ZHOU Hai, CHEN Hao, GUO Ya, KANG Min. Synthesis of Meso-porous Co₃O₄ Polyhedra and Their Electrochemical Properties^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1374.

Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)₂(H₂O)₂] ₂· [Mo₄^Ⅴ Mo₄^ⅥV₈^ⅣO₄₀ (AsO₄)] Containing Different Coordinated Cations

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments