Studies on the Structure of Tricyclohexyltin- 2-(12-dithioethylene)methylene-3-oxo-5-aryl-4-pentenicate

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (10): 1667.

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Studies on the Structure of Tricyclohexyltin- 2-(12-dithioethylene)methylene-3-oxo-5-aryl-4-pentenicate

LI Jian-Xin¹, XIAO You-Ping², LIU Qun¹, ZHAO Bao-Zhong¹, LIU Jing-Fu¹

1. Department of Chemistry, Northeast Normal University, Changchun 130024, China;
2. Department of Chemistry, Changchun Education College, Changchun 130061, China;
3. Changchun Instituteof Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2000-08-29 Online:2001-10-24 Published:2001-10-24

Abstract

Abstract: Three title compounds were prepared and the structure of title compound 2 was characterized by IR, ¹H NMR, ¹³C NMR, ¹¹⁹Sn NMRspectroscopy and the crystal structure of compound 2a was determined by Xray analysis with the final Rindices[ I>2σ(I)] R₁=0.0350 and R₂,ω=0.0888. The crystal of compound 2a belongs to triclinic system, space group P1 with a=10598(6) nm, b=13074(10) nm, c=13786(10) nm, α=62666 (7)°, β=72530(2)°, γ=80680(2)°, V=16180 nm³, D_x=1444 g·cm^-3, Z=1, F (000)=728. The bond length of Sn₁_O₁ is 0.2076 nm and Sn 1... O₂ distance is 0.3013 nm. The coordination about the tin atom can be considered as a distorted tetrahedral. The detail values of ¹H NMR, ¹³C NMR, ¹¹⁹Sn NMR, ²J ¹¹⁹Sn₁Hand J ¹¹⁹Sn₁₃ Cwere obtained. δ ¹¹⁹Sn=23.836, ²J ¹¹⁹Sn₁H=88.0 Hz, ¹J _{¹¹⁹Sn₁₃} C=347.1 Hz, ²J ¹¹⁹Sn₁₃ C=45.6 Hz.

Key words: Tricyclohexyltin-2-(12 dithioethylene)methylene-3-oxo-5-aryl-4-pentenicate, Syntheses, X-ray analysis, Structure

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LI Jian-Xin, XIAO You-Ping, LIU Qun, ZHAO Bao-Zhong, LIU Jing-Fu . Studies on the Structure of Tricyclohexyltin- 2-(12-dithioethylene)methylene-3-oxo-5-aryl-4-pentenicate[J]. Chem. J. Chinese Universities, 2001, 22(10): 1667.

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Studies on the Structure of Tricyclohexyltin- 2-(12-dithioethylene)methylene-3-oxo-5-aryl-4-pentenicate

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