Synthesis and Crystal Structure of [N(CH3)4]4 [H5PMo5V9O42 ] ·3.5H2O Containing Mixed valence Vanadium

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (8): 1180.

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Synthesis and Crystal Structure of [N(CH₃)₄]₄ [H₅PM_o₅V₉O₄₂ ] ·3.5H₂O Containing Mixed valence Vanadium

XU Jia-Ning¹, YANG Guo-Yu¹, LIN Ying-Jie¹, SHI Zhan¹, YU Jie-Hui¹, FENG Shou-Hua¹, XU Ji-Qing¹, XU Xin², LI Yan², CUI Xiao-Hui², HUANG Xiao-Ying³, YANG Lan-Ping³

1. Department of Chemistry, Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China;
2. Changchun Universityof Scienceand Technology, Changchun 130026, China;
3. State Key Laboratoryof Structural Chemistry, Fujian Instituteof Researchon the structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:1999-09-23 Online:2000-08-24 Published:2000-08-24

Abstract

Abstract: The title compound [N(CH₃)₄]₄[H₅PMo₅V₉O₄₂] ·3.5H₂Owas synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a bicapped Keggin polyanion, two vanadium atoms are distributed at two capping metal atom positions. The crystal is monoclinic, space group C₂/c with a=1.2848(4) nm, b=2.3664(4) nm, c=2.1136(4) nm, β= 90.69(2)°, V=6.425(4) nm 3, Z=4, Dc=2.07 g·cm^-3, R=0.066, R_w=0.069, S=1.33, {(Δ/σ)_max=}004, {(Δρ)_max =}91 e·nm^-3.

Key words: Hydrothermal synthesis, Crystal structure, Mixed valence

CLC Number:

O614

TrendMD:

XU Jia-Ning, YANG Guo-Yu, LIN Ying-Jie, SHI Zhan, YU Jie-Hui, FENG Shou-Hua, XU Ji-Qing, XU Xin, LI Yan, CUI Xiao-Hui, HUANG Xiao-Ying, YANG Lan-Ping . Synthesis and Crystal Structure of [N(CH₃)₄]₄ [H₅PM_o₅V₉O₄₂ ] ·3.5H₂O Containing Mixed valence Vanadium[J]. Chem. J. Chinese Universities, 2000, 21(8): 1180.

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Synthesis and Crystal Structure of [N(CH₃)₄]₄ [H₅PM_o₅V₉O₄₂ ] ·3.5H₂O Containing Mixed valence Vanadium

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