Application of Dynamical Lie Algebraic Method Combining Intermediate Picture to Energy Transfer in A+BC Collinear Collision

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (5): 776.

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Application of Dynamical Lie Algebraic Method Combining Intermediate Picture to Energy Transfer in A+BC Collinear Collision

YANG Ben-Hui¹, DING Shi-Liang², HAN Ke-Li¹

1. State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
2. Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China

Received:1999-03-24 Online:2000-05-24 Published:2000-05-24

Abstract

Abstract: Under the semiclassical approximation, we apply the dynamical Lie algebraic method combining with intermediate picture to study energy transfer in the atom-anharmonic oscillatorcollinear collision. By using the first order approximation of group parameterswe solve the motion equation of group parameters and obtain the time evolution operator. As an example, the scattering system H₂₊He is considered. Our results are in good agreement with those obtained by the exact quantum mechanics calculations.

Key words: Dynamical Lie algebra, Intermediate picture, Energy transfer, Transition probability

CLC Number:

O643

TrendMD:

YANG Ben-Hui, DING Shi-Liang, HAN Ke-Li . Application of Dynamical Lie Algebraic Method Combining Intermediate Picture to Energy Transfer in A+BC Collinear Collision[J]. Chem. J. Chinese Universities, 2000, 21(5): 776.

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Application of Dynamical Lie Algebraic Method Combining Intermediate Picture to Energy Transfer in A+BC Collinear Collision

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