Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (6): 846.

• Articles • Previous Articles     Next Articles

Synthesis and Characterization for Complex η2-C60[RhCl(CO)(PPh3)2]

WU Zhen-Yi, CHENG Da-Dian, YANG Shi-Yao, LIN Yong-Sheng, ZHAN Meng-Xiong, ZHENG Lan-Sun   

  1. Department of Chemstry, Xiamen University, Xiamen, 361005
  • Received:1998-09-14 Online:1999-06-24 Published:1999-06-24

Abstract: The fullerene complex,η2-C60[RhCl(CO)(PPh3)2], has been prepared by the reaction of C60with RhCl(CO)(PPh3)2in benzene at room temperature. The new complex was characterized by elemental analysis, IR, XPS and electronic spectra. The result show that the complex of 2 form can be formed by C60bonding to RhCl(CO)(PPh3)2in the σ-π way. In addition, the complex structure has been supposed.

Key words: C60[RhCl(CO)(PPh3)2], Synthesis, Characterization

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