Emulsion Polymerization of MMA/BA in the Presence of Ionic Surface Active Monomers(Ⅰ)--Syntheses and Polymerization Reactivities of the Surfmers

Abstract

Abstract: Two surface active ionic monomers(surfmers)[sodium sulfonated lauryl(allyl glyceryl) succinate(ZC-L) and sodium sulfonated lauryl(methacryloyl glyceryl) succinate(ZD-L)] were synthesized and used in the emulsion copolymerization of methyl methacrylate(MMA) and butyl acrylate(BA). The investigation was emphasized particularly on ZC-L for its molecular structure, surface tension behavior and the reactivity for homo and copolymerization. The surface tensions of MMA/BA/Surfmer, MMA/Surfmer and BA/Surfmer copolymer latexes were remarkably higher than that of MMA/BA/sodium dodecyl benzene sulfonate copolymer latex, while similar to or higher than that of MMA/BAemulsifier-free copolymer latex, indicating that the surfmers were covalently bonded on polymer latex particles, and there is only a little remained in the aqueous solution. The ZC-Lcopolymerization reactivity with MMA/BA is better than that of ZD-L.

Key words: Acrylate, Emulsion polymerization, Surface active monomer, Syntheses, Polymerization reactivity

CLC Number:

O631

TrendMD:

ZHANG Mao-Gen, WENG Zhi-Xue, HUANG Zhi-Ming, MAO Xin, PAN Zu-Ren . Emulsion Polymerization of MMA/BA in the Presence of Ionic Surface Active Monomers(Ⅰ)--Syntheses and Polymerization Reactivities of the Surfmers[J]. Chem. J. Chinese Universities, 1999, 20(12): 1969.

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Emulsion Polymerization of MMA/BA in the Presence of Ionic Surface Active Monomers(Ⅰ)--Syntheses and Polymerization Reactivities of the Surfmers

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