Chem. J. Chinese Universities ›› 2019, Vol. 40 ›› Issue (6): 1193.doi: 10.7503/cjcu20190084
• Physical Chemistry • Previous Articles Next Articles
FAN Ye, LIU Tingting, FANG Yun(), XIA Yongmei
Received:
2019-01-29
Online:
2019-06-10
Published:
2019-05-11
Supported by:
CLC Number:
TrendMD:
FAN Ye,LIU Tingting,FANG Yun,XIA Yongmei. Vesiculation and Stability: Oligomer of Conjugated Linoleate Acids Prepared by High Internal Phase Self-emulsion Polymerization†[J]. Chem. J. Chinese Universities, 2019, 40(6): 1193.
Fig.2 Effect of reaction conditions on oligomerization of CLA by thermal polymerization (A) Dosage of CLA(APS: 3%, SCL: 16.6%); (B) dosage of SCL(APS: 3%, CLA: 60%); (C) dosage of initiator based on CLA(SCL: 16.6%, CLA: 60%). All reactions were initiated by APS for 20 h at 80 ℃, and initial dose of CLA was 4 g.
Fig.3 UV spectra of the oligomerization products of CLA at 80 ℃ for 20 h a. Pre-initiated by APS(3%); b. post-initiated by APS(3%); c. post-initiated by APS(1.5% + 1.5%).
Fig.6 Vesicle stability of the FAV assembling by 3 mmol/L oligo-CLA (A) Acid resistance. a. Pre-oligomerization; b. post-oligomerization. The digital photographs of post-oligomerization(B) and preoligomerization(C) at different concentrations of SDS. c(SDS)/(g·L-1): (B1) 0.01(cloudy); (B2) 0.02(cloudy); (B3) 0.04(clear); (B4) 0.06(clear); (C1) 0.06(precipitation); (C2) 0.10(cloudy); (C3) 0.18(cloudy); (C4) 0.25(semitransparent).
Fig.7 Size distribution(A) and the corresponding TEM images(B—E) of FAV assembling by oligo-CLA(3 mmol/L, pH=13) with total crosslinking degree of 33% (A) c(Ca2+)/(mmol·L-1): a. 0, b. 0.3, d. 0.6, d. 0.9, e. 1.2; (B) c(Ca2+)=0.3 mmol/L; (C) c(Ca2+)=0.6 mmol/L; (D) c(Ca2+)=0.9 mmol/L; (E) c(Ca2+)=1.2 mmol/L.
Fig.8 SI-pH curves(A, B) of composite systems(cCLA=3 mmol/L), TEM images of hybrid vesicles of oligo-CLA/Span 40(x=0.05,pH=5.2)(C) and oligo-CLA/AEO2(x=0.09, pH=5.6)(D) (A) a. CLA/Span 40, x=0.05; b. oligo-CLA/Span 40, x=0.05; c. oligo-CLA. (B) a. CLA/AEO2, x=0.09; b. oligo-CLA/AEO2, x=0.09; c. oligo-CLA.
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