Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (5): 1084.doi: 10.7503/cjcu20160675
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YANG Zewen, ZHANG Yanyan, FU Feiya, LIU Xiangdong*
Received:
2017-10-12
Online:
2018-03-12
Published:
2018-03-12
Contact:
LIU Xiangdong
Supported by:
CLC Number:
TrendMD:
YANG Zewen,ZHANG Yanyan,FU Feiya,LIU Xiangdong. Preparation and Properties of a Bio-based Unsaturated Polyester Resin Glue and Its Cotton Fabric-reinforced Composite†[J]. Chem. J. Chinese Universities, 2018, 39(5): 1084.
Resin glue | m(GMA)/g | m(AESO)/g | m(UPOEM)b/g | Viscosity/(mPa·s)(30 ℃) | Bio-based content(%) | Gel content(%) |
---|---|---|---|---|---|---|
UPR1 | 100 | 0 | 400 | 772±34 | 80 | 97.3 |
UPR2 | 100 | 100 | 300 | 723±12 | 79.5 | 94.1 |
UPR3 | 100 | 200 | 200 | 695±14 | 78.9 | 93.1 |
UPR4 | 100 | 300 | 100 | 572±20 | 78.4 | 92.5 |
UPR5 | 100 | 400 | 0 | 427±19 | 77.9 | 90.4 |
UPR6 | 50 | 200 | 200 | 1432±29 | ||
UPR7 | 200 | 200 | 200 | 292±2 | ||
UPR8 | 0 | 100 | 300 | 13406±218 | ||
UPR9 | 0 | 200 | 200 | 9450±263 | ||
UPR10 | 0 | 300 | 100 | 5400±384 |
Table 1 Composition ratio, viscosity, bio-based content and gel content for the UPOEM resin gluesa
Resin glue | m(GMA)/g | m(AESO)/g | m(UPOEM)b/g | Viscosity/(mPa·s)(30 ℃) | Bio-based content(%) | Gel content(%) |
---|---|---|---|---|---|---|
UPR1 | 100 | 0 | 400 | 772±34 | 80 | 97.3 |
UPR2 | 100 | 100 | 300 | 723±12 | 79.5 | 94.1 |
UPR3 | 100 | 200 | 200 | 695±14 | 78.9 | 93.1 |
UPR4 | 100 | 300 | 100 | 572±20 | 78.4 | 92.5 |
UPR5 | 100 | 400 | 0 | 427±19 | 77.9 | 90.4 |
UPR6 | 50 | 200 | 200 | 1432±29 | ||
UPR7 | 200 | 200 | 200 | 292±2 | ||
UPR8 | 0 | 100 | 300 | 13406±218 | ||
UPR9 | 0 | 200 | 200 | 9450±263 | ||
UPR10 | 0 | 300 | 100 | 5400±384 |
Fig.5 Storage modulus(E', A) and loss factor(tanδ, B) of C-UPR1(a), C-UPR2(b), C-UPR3(c), C-UPR4(d) and C-UPR5(e)Note:Inset of (A): E' of C-UPR1(a), C-UPR2(b), C-UPR3(c), C-UPR4(d) and C-UPR5(e) at 25 ℃; inset of (B): Tg of C-UPR1(a), C-UPR2(b), C-UPR3(c), C-UPR4(d) and C-UPR5(e).
Compositea | 10-3 | ||
---|---|---|---|
C-UPR1 | 78.6 | 248.3 | 17.92 |
C-UPR2 | 74.6 | 263.5 | 14.97 |
C-UPR3 | 71.5 | 272.5 | 10.03 |
C-UPR4 | 56.8 | 290.3 | 7.04 |
C-UPR5 | 55.8 | 295.8 | 6.74 |
Table 2 Crosslink density and thermal properties of the C-UPR1—C-UPR5
Compositea | 10-3 | ||
---|---|---|---|
C-UPR1 | 78.6 | 248.3 | 17.92 |
C-UPR2 | 74.6 | 263.5 | 14.97 |
C-UPR3 | 71.5 | 272.5 | 10.03 |
C-UPR4 | 56.8 | 290.3 | 7.04 |
C-UPR5 | 55.8 | 295.8 | 6.74 |
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