Effect of Electron Radiation on Crystal Structure Transition of trans-1,4-Polybutadiene

Abstract

Abstract: trans 1,4-Polybutadiene(PTBD) was synthesized by rare earth catalyst system. The effect of electron radiation on phase transition from monoclinic phase to hexagonal phase was observed by TEM. Electron diffraction patterns of monoclinic phase, hexagonal phase and two coexistent phases were recorded. The mechanism of phase transition was also discussed in this paper.

Key words: Electron radiation, trans-1,4-Polybutadiene, Crystal structure, Phase transition

CLC Number:

O631

TrendMD:

CAI Jia-Li, LI Gao, YANG Xiao-Niu, SU Feng-Yu, DONG Wei-Min, ZHOU En-Le . Effect of Electron Radiation on Crystal Structure Transition of trans-1,4-Polybutadiene[J]. Chem. J. Chinese Universities, 1999, 20(11): 1811.

References

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