A Study on the Micelle and Phase Separation Behavior of NIPAM-ODA Copolymer in Aqueous Solution

Abstract

Abstract: To study the micele and phase separation behavior of amphiphilic copolymer in aqueous solution which is temperat ure-sensit ive, The copolymer of N-isopropylacrylamide(NIPAM)and octadecyl acrylate(ODA)was syn The sized.The micelle behavior of The copolymer was studied by drop weight method and fluorescence probe method respectively.Simultaneously, the phe-nomenon of LCST(Lower Crit ical Solution Temperat ure)of The copolymer in aqueous solution with The increase of temperat ure was also studied by using fluorescence probe met hod.results showed that, the phase separation came into being in The aqueous solution of the copolymer when temperature was increased to its LCST.The P-Aisotherms of The molecule of The copolymer as insoluble monolayer on water surface was obt ained by L-Bmet hod.The abnormal phenomenon that the monolayer of The copolymer got coacervat ive more and more with the increase of The tem-perat ure was observed.It further indicated that The phase separation of the copolymer occured from anoTher met hod.This phenomenon was also discussed in detail.

Key words: Water soluble polymer, Phase separation, Fluorescence probe, P-Aisotherms

CLC Number:

O631

TrendMD:

SHI Xiang-Yang, LI Jun-Bai, SUN Cao-Min WU Shi-Kang . A Study on the Micelle and Phase Separation Behavior of NIPAM-ODA Copolymer in Aqueous Solution[J]. Chem. J. Chinese Universities, 1999, 20(1): 135.

References

Related Articles 15

[1]	TANG Yuanhui, LI Chunyu, LIN Yakai, ZHANG Chunhui, LIU Ze, YU Lixin, WANG Haihui, WANG Xiaolin. Dissipative Particle Dynamics Simulation of the Effect of Polymer Chain Rigidity on Membranes Formation by Nonsolvent Induced Phase Separation Process [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220169.
[2]	LIN Ningqin, YAO Ke, CHEN Xiangjun. Research Progress of Molecular Recognition and Interaction of Crystallins Linking Cataract [J]. Chem. J. Chinese Universities, 2021, 42(11): 3379.
[3]	ZHENG Qiuguang,LIU Hailiang,XIAO Changfa. Preparation and Performance of Poly(vinylidene chloride-co-vinyl chloride) Porous Membranes via Thermally Induced Phase Separation^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 841.
[4]	Yingying ZHANG,Yiwen HUANG,Bing ZHAO,Liyan WANG,Bo SONG. Synthesis of a Colorimetric Fluorescent Probe of Cr ³⁺ and Its Application in Cell Imaging ^† [J]. Chem. J. Chinese Universities, 2019, 40(12): 2486.
[5]	YU Zhaochuan, MA Wenhui, WU Tao, WEN Jing, ZHANG Yong, WANG Liyan, CHU Hongtao. Preparation of B, N, S co-Doped Graphene Quantum Dots for Fluorescence Detection of Fe ³⁺ and H₂P $O 4 - †$ [J]. Chem. J. Chinese Universities, 2019, 40(11): 2286.
[6]	HUANG Chibao,PAN Qi,CHEN Huashi,LIANG Xing,LÜ Guoling. Dicyanostilbene-derived Two-photon Fluorescence Probe for Lead Ions^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 897.
[7]	HAN Ruixia,LÜ Jitao,ZHANG Shuzhen. Molecular Probe for the Determination of Hydroxyl Radicals in Heterogeneous Systems: Coumarin^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2658.
[8]	LU Zhiwei, CHEN Shun, JU Yanyun, ZHANG Yang, XIONG Chuanxi, DONG Lijie. Synthesis and Properties of PS-b-P(DMS-stat-VMS) Block Copolymer [J]. Chem. J. Chinese Universities, 2017, 38(8): 1484.
[9]	XU Wanzhen, QIU Chunxiao, HUANG Weihong, LIU Hong, YANG Wenming. Computer Simulation Design, Preparation and Application of Fluorescence Sensors Based on Quantum Dots for Selective Detection of 4-Nitrophenol in River Water^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1155.
[10]	HUANG Chibao, PAN Qi, CHEN Xiaoyuan, ZHAO Guanglian, CHEN Huashi, LIANG Xing, LÜ Guoling. Dicyanostilbene-derived Two-photon Fluorescence Probe for Mercury Ions^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1751.
[11]	XU Fanhua, HENG Xiao, REN Jianxue, ZHOU Hengwei. Simulation Study of the Phase Separation and Self-assembly of Nanoparticles Coated with Ligands^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1115.
[12]	WANG Caiping, LI Youfen, ZHANG Yidong. Preparation of Glass Ceramics Containing CaF₂ by One-step Method and Analysis of the Fluorescent Probe of Eu³⁺ Ion^† [J]. Chem. J. Chinese Universities, 2016, 37(4): 607.
[13]	SONG Chunxia, YANG Xiaohai, WANG Kemin, WANG Qing, LIU Jianbo, HUANG Jin, LI Wenshan, HUANG Haihua, LIU Wei. Application of Polymers in Fluorescence Analysis^† [J]. Chem. J. Chinese Universities, 2016, 37(2): 201.
[14]	MI Xiaolong, JIAO Xiaojie, LIU Chang, HE Song, ZENG Xianshun. Rhodamine-based Cell Permeable Fluoresecent Turn-on Probes for Cupric Ion^† [J]. Chem. J. Chinese Universities, 2016, 37(10): 1784.
[15]	ZHAO Ziliang, LI Qi, XUE Yanhu, JI Xiangling, BO Shuqin, LIU Yonggang. Composition and Molecular Weight Determination of Aqueous Two-phase System by Quantitative Size Exclusion Chromatography^† [J]. Chem. J. Chinese Universities, 2016, 37(1): 167.