Hydrolysis of Lipophilic Amino Acid Esters Catalyzed by Metallomicelles

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (S1): 470.

• Physical Organic Chemistry • Previous Articles Next Articles

Hydrolysis of Lipophilic Amino Acid Esters Catalyzed by Metallomicelles

Xiao-Qi Yu, Jing Song You, Qing-Xiang Xiang, Qian-Shun Yan, Ru-Gang Xie

Department of Chemistry, Sichuan University, Chengdu 610064

Online:1998-12-31 Published:1998-12-31
Supported by:
NSFC (No.29502008)

Abstract

Abstract: Metallomicelles as the model of hydrolytic metalloenzymes have begun recently¹. Examples are the metal-ion complexes of lipophilic imidazoles² and pyridines³ co-micelled with surfactants. Herein we report the complexes of a novel macrocyclic 12-membered di-oxotetraamine ligand bearing bis-hydroxy groups as functional pendants which can mimic the catalytic function of carboxypeptidase A in micellar media.

Key words: metallomicelles, lipophilic complexes, amino acid esters, hydrolysis

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Xiao-Qi Yu, Jing Song You, Qing-Xiang Xiang, Qian-Shun Yan, Ru-Gang Xie. Hydrolysis of Lipophilic Amino Acid Esters Catalyzed by Metallomicelles[J]. Chem. J. Chinese Universities, 1998, 19(S1): 470.

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Hydrolysis of Lipophilic Amino Acid Esters Catalyzed by Metallomicelles

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