Studies on Syntheses and Spectral Character of Bis[N,N'-alkylene-2,2-(arylmethylene)bis(3,4-dimethyl pyrrole-5-aldimino)] Dimanganese(Ⅱ) and Their Biomimetic Catalytic Character for the Monooxygenation of Cyclohexane with PhIO

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (7): 1065.

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Studies on Syntheses and Spectral Character of Bis[N,N'-alkylene-2,2-(arylmethylene)bis(3,4-dimethyl pyrrole-5-aldimino)] Dimanganese(Ⅱ) and Their Biomimetic Catalytic Character for the Monooxygenation of Cyclohexane with PhIO

CHEN Xin-Bin¹, GUI Ming-De¹, ZHU Shen-Jie¹, GUO Can-Cheng²

1. Department of Chemistry, Nankai University, Tianjin, 300071;
2. Dept. of Chemistry and Chemical Engin. Hunan University, Changsha, 410082

Received:1997-06-09 Online:1998-07-24 Published:1998-07-24

Abstract

Abstract: This paper first reports the syntheses and spectral character of bis[N,N'-alkylene-2,2-(phenylmethylene)bis(3,4-dimethylpyrrole-5-aldimine)](alkylenes: 1,3-propylene; 1,4-butylene; 1,2-phenylene; 4-methyl-1,2-phenylene), bis[N,N'-(1,2-ethylene)2,2-(4-methoxyphenylmethylene)bis(3,4-dimethylpyrrole-5-aldimine)] and their dimanganese(Ⅱ) complexes as well as the biomimetic catalytic properties of the complexes for the monooxygenation of cyclohexane with PhIO.

Key words: Schiff bases, Syntheses, Spectra, Biomimetic catalysis, Oxidation

CLC Number:

O627.7

TrendMD:

CHEN Xin-Bin, GUI Ming-De, ZHU Shen-Jie, GUO Can-Cheng . Studies on Syntheses and Spectral Character of Bis[N,N'-alkylene-2,2-(arylmethylene)bis(3,4-dimethyl pyrrole-5-aldimino)] Dimanganese(Ⅱ) and Their Biomimetic Catalytic Character for the Monooxygenation of Cyclohexane with PhIO[J]. Chem. J. Chinese Universities, 1998, 19(7): 1065.

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Studies on Syntheses and Spectral Character of Bis[N,N'-alkylene-2,2-(arylmethylene)bis(3,4-dimethyl pyrrole-5-aldimino)] Dimanganese(Ⅱ) and Their Biomimetic Catalytic Character for the Monooxygenation of Cyclohexane with PhIO

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