Synthesis, Properties and Crystal Structure of Organic-inorganic Radical Salt(DBTTF)6HPMo12 O40·2H2O

Abstract

Abstract: Organic inorganic radical salt(DBTTF)₆PMo₁₂O₄₀ ·2H₂O was synthesized by electrocrystallization and characterized by IR spectrum, electronic spectrum and ESR technology. Its magnetic property, conductivity and crystal structure were determined. The title compound crystallized in a triclinic system with P1 space group, a =1.3787(7), b =1.4204(2), c =1.5702(2) nm, α =104.57(1)°, β =103.41(2)°, γ =95.80(2)°, V =2.853(2) nm³, Z =1 and a final R =0.0727.

Key words: Organic inorganic radical salt, Molybdophosphateheteropoly anion, Dibenzotetrathiofulvalene, Crystal structure

CLC Number:

O641.4

TrendMD:

CHEN Ya-Guang, LIU Jing-Fu, LIN Yong-Hua, XING Yan, JIA Heng-Qing . Synthesis, Properties and Crystal Structure of Organic-inorganic Radical Salt(DBTTF)₆HPMo₁₂ O₄₀·2H₂O[J]. Chem. J. Chinese Universities, 1998, 19(6): 843.

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Synthesis, Properties and Crystal Structure of Organic-inorganic Radical Salt(DBTTF)₆HPMo₁₂ O₄₀·2H₂O

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