Synthesis, Crystal Structure and Characterization of [Zn(dpa)(PPr)2]·2H2O

Abstract

Abstract: The zinc(Ⅱ) complex [Zn(dpa)(PPr)₂]·2H₂O was prepared and its crystal structure was determined. The crystal belongs to triclinic, space group P1,with the crystal cell parameters: a=10.541(1) nm, b=11.333(1) nm, c=11.698(1) nm, α=91.00(1)°, β=90.96(1)°, γ=88.38(1)°, Z=2. Four carboxyl oxygen atoms from two PPr^- and two nitrogen atoms from dpa coordinate with Zn(Ⅱ) respectively to form a distorted octahedral. Intramolecular hydrogen bonds were observed involving two water molecules and the coordinated atoms. The complex was characterized by elementary analyses, IR, molar conductance and differential thermal analyses.

Key words: Zinic complex, Crystal structure, Characterization

CLC Number:

O614

TrendMD:

FENG Xu-Wen, GONG Yu-Qiu, GU Jian-Ming . Synthesis, Crystal Structure and Characterization of [Zn(dpa)(PPr)₂]·2H₂O[J]. Chem. J. Chinese Universities, 1998, 19(5): 681.

References

Related Articles 15

[1]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[2]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[3]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[4]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[5]	GENG Chuannan, HUA Wuxing, LING Guowei, TAO Ying, ZHANG Chen, YANG Quanhong. Catalysis in Li-sulfur Battery： Materials and Characterization [J]. Chem. J. Chinese Universities, 2021, 42(5): 1331.
[6]	MA Chao, LIU Xiaona, NIE Chenyang, CHEN Lu, TIAN Peng, XU Hongyi, GUO Peng, LIU Zhongmin. Applications of X-ray and Electron Crystallography in Structural Investigations of Zeolites [J]. Chem. J. Chinese Universities, 2021, 42(1): 188.
[7]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[8]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[9]	ZHAO Xingling, QI Guodong, WANG Qiang, CHU Yueying, GAO Wei, LI Shenhui, XU Jun, DENG Feng. Structure， Nature and Activity of Ga Species for Propane Aromatization in Ga/ZSM-5 Revealed by Solid-state NMR Spectroscopy [J]. Chem. J. Chinese Universities, 2020, 41(12): 2681.
[10]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[11]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[12]	ZHANG Jian,ZHU Zhaowu,LEI Ze,WANG Lina,CHEN Desheng,YI Aifei,SU Hui,QI Tao. Preparation of Vanadium Oxalate by Solvent Extraction and Purification with P507 and Its Physicochemical Properties^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 740.
[13]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[14]	TIAN Huan, ZHANG Menglong, WANG Lisha, TONG Bihai, ZHAO Zhuo. Synthesis of 4,13-Dithio Benzene and-18-Crown-6 and Its Selective Extractability on A $g + †$ [J]. Chem. J. Chinese Universities, 2018, 39(6): 1191.
[15]	ZHU Lei,HAN Junyan,CHANG Haizhen,QIU Yuyuan,ZHANG Yanan,PENG Danni,HU Wei,MIAO Shaobin. Different Pathways for the Cyclocondensation Reactions of 1,2-Diamine and 1,2-Diketone^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2686.

Synthesis, Crystal Structure and Characterization of [Zn(dpa)(PPr)₂]·2H₂O

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments