Hydrothermal Synthesis and Crystal Structure of the Sodium Vanadyl Phosphate NaVPO5

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (12): 1891.

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Hydrothermal Synthesis and Crystal Structure of the Sodium Vanadyl Phosphate NaVPO₅

PANG Guang-Sheng¹, FENG Shou-Hua¹, XU Ru-Ren¹, Hong Mao-chun²

1. Key Laboratory of Inorganic Hydrothermal Synthesis, Department of Chemistry, Jilin University, Changchun, 130023;
2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, State Key Laboratory of Strurtural Chemistry, Fuzhou, 350002

Received:1997-10-09 Online:1998-12-24 Published:1998-12-24

Abstract

Abstract: Dark red single crystal of sodium vanadyl phosphate NaVPO₅ has been synthesized by hydrothermal synthesis method and its structure has been characterized by single-crystal X-ray methods. It crystallizes in monoclinic space group P2₁ /c with a =06527(2) nm, b =0.8462(2) nm, c =0.7120(2) nm, β =1.1523(3)°, V =0.33570 nm³, Z =4. The strutrure was solved by Direct Method and refined by the least saqures with R =0057 and R_W=0.062. The structure can be described as a “VPO₅” framework which is build up from corner sharing VO₆ octahedron parallel to the c axis. Each PO₄ tetrahedron shares its corners with four VO₆ octahedron, two of them belong to the same chain, and each VO₆ octahedron share its corners with four PO₄ tetrahedron and two VO₆ octahedron.

Key words: Hydrothermal synthesis, Sodium vanadyl phosphate, Crystal structure

CLC Number:

O612.5

TrendMD:

PANG Guang-Sheng, FENG Shou-Hua, XU Ru-Ren, Hong Mao-chun. Hydrothermal Synthesis and Crystal Structure of the Sodium Vanadyl Phosphate NaVPO₅[J]. Chem. J. Chinese Universities, 1998, 19(12): 1891.

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Hydrothermal Synthesis and Crystal Structure of the Sodium Vanadyl Phosphate NaVPO₅

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