Microwave Assisting Solid Phase Organic Reaction Monitored by FTIR

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (10): 1608.

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Microwave Assisting Solid Phase Organic Reaction Monitored by FTIR

YU Ai-Ming¹, ZHANG Zheng-Pu², YANG Hua-Zheng¹, ZHANG Chun-Xiang¹, LIU Zhun¹

1. State Key Laboratory of Elemento Organic Chemistry, Nankai University, Tianjin, 300071;
2. State Key Laboratory of Functional Polymeric Materials for Adsorption and Separation, Nankai University, Tianjin, 300071

Received:1997-09-17 Online:1998-10-24 Published:1998-10-24

Abstract

Abstract: Microwave assisting the addition reaction of Wang resin bound secondary amine 1 and isocyanate was carried out for the first time. The reaction time course was determined by analyzing FTIRspectra obtained using the improved KBr pellet method by grinding down the resin beads prior to recording. The results showed that the reaction assisted by microwave was accomplished only in 12min, while the reaction without microwave was completed in 210min.

Key words: Solid phase organic reaction, Microwave irradiation, FTIR, Resin beads

CLC Number:

O621.3

TrendMD:

YU Ai-Ming, ZHANG Zheng-Pu, YANG Hua-Zheng, ZHANG Chun-Xiang, LIU Zhun . Microwave Assisting Solid Phase Organic Reaction Monitored by FTIR[J]. Chem. J. Chinese Universities, 1998, 19(10): 1608.

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Microwave Assisting Solid Phase Organic Reaction Monitored by FTIR

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