Synthesis and Characterization of (5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieno)Nickel Bis(O,O'-dialkyldithiophosphate)

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (1): 74.

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Synthesis and Characterization of (5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieno)Nickel Bis(O,O'-dialkyldithiophosphate)

XIE Bin¹, WU Shi-Ye²

1. Department of Basic Science, Sichuan Institute of Light Industry and Chemical Technology, Zigong, 643033;
2. Department of Light Industry, Sichuan Institute of Light Industry and Chemical Technology, Zigong, 643033

Received:1997-01-26 Online:1998-01-24 Published:1998-01-24

Abstract

Abstract: Four nickel complexes [Ni (hmtade) {SSP (OR)₂}₂] (hmtade=5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradeca-4, 11-diene; R=phenyl, 2-naphthyl, 2-phenylethyl and cyclohexyl) were synthesized and characterized by elemental analysis, molar conductivity, infrared spectra, electronic spectra, NMR spectra (¹H and ³¹P) and TG-DTA analysis. The results indicate that all complexes are non-electrolysis in DMSO and O,O'-dialkyldithiophosphoric acid radicals as monodentate ligands coordinate to nickel atom. The tetraazamacrocyclic configuration and the TG-DTA curves of complexes are also discussed.

Key words: Tetraazamacrocycle, O, O'-Dialkyldithiophosphate, Coordination, Configuration

CLC Number:

O627

TrendMD:

XIE Bin, WU Shi-Ye . Synthesis and Characterization of (5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieno)Nickel Bis(O,O'-dialkyldithiophosphate)[J]. Chem. J. Chinese Universities, 1998, 19(1): 74.

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Synthesis and Characterization of (5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieno)Nickel Bis(O,O'-dialkyldithiophosphate)

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