Synthesis, Characterization and Structure of Tetrabenzoyloxy Bridged Binuclear Eu(Ⅲ) Complex

Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (12): 1917.

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Synthesis, Characterization and Structure of Tetrabenzoyloxy Bridged Binuclear Eu(Ⅲ) Complex

NIU Shu-Yun¹, YANG Bing², CAO Jin-Quan², YANG Guang-Di³, BU Wei-Min³

1. Department of Chemistry, Liaoning Normal University, Dalian, 116029;
2. Department of Chemistry, Jilin University, Changchun, 130023;
3. Institute of Theoretical Chemistry, Jilin University, Changchun, 130023

Received:1996-11-28 Online:1997-12-24 Published:1997-12-24

Abstract

Abstract: The crystal of complex [Eu₂(phen)₂(C₆H₅COO)₆] was synthesized and its struc-ture of the single crystal was determined by X-ray diffraction.The crystal belongs to a tri-clinlc system, space group P1, with a=1.08156(7) nm, b=1.19331(7) nm, c=1.24401(8) nm, a=104.972(5)o, g=93.661 (5)o, y=113.297(5), V=1.3994(2) nm³,Z=1, R=0.0437, R_w=0.0414.UV-Vis and IR spectra of the complex were determinedand discussed.

Key words: Eu(Ⅲ) complex, Crystal structure, UV-Vis spectrum, IR spectrum

CLC Number:

O614.33

TrendMD:

NIU Shu-Yun, YANG Bing, CAO Jin-Quan, YANG Guang-Di, BU Wei-Min. Synthesis, Characterization and Structure of Tetrabenzoyloxy Bridged Binuclear Eu(Ⅲ) Complex[J]. Chem. J. Chinese Universities, 1997, 18(12): 1917.

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Synthesis, Characterization and Structure of Tetrabenzoyloxy Bridged Binuclear Eu(Ⅲ) Complex

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