Crystal Structure of Dicarbonyl (η5-2, 4-Cyclopentadien-1-yl) tricyclohexylstannyliron

Abstract

Abstract: The title complex Cp (CO)₂FeSn(C₆H₁₁)₃ was synthesized and it's crystal structurewas determined by four-circle X-ray diffra tometer.The crystal belongs to monoclinic system, space group C₂/c with parameters: a=1.9476 (4) nm, b=0.8826 (2) nm, c=2.9158(6) nm, β= 95.49(3)°, Z=4.The two carbonyl groups attached to iron atom lie inabout right angles to each other and to the tin-iron axis.The three-fold axis passing throughthe iron atom and relating these three ligand directions is almost perpendicular to the plane ofthe cyclopentadienyl ring.The co-ordination of ligands around the tin atom is close to tetrahedral.The cyclohexyls are all in stable chair-conformations.

Key words: Tin-iron bond, Isonuclues double metal complex, Crystal structure

CLC Number:

O641

TrendMD:

YAN Peng-Fei, LE Zheng-Yu, GAO Jin-Sheng, CHI Shu-Liang, BU Wei-Ming, FAN Yu-Guo, YE Ling, YANG Guang-Di. Crystal Structure of Dicarbonyl (η⁵-2, 4-Cyclopentadien-1-yl) tricyclohexylstannyliron[J]. Chem. J. Chinese Universities, 1997, 18(11): 1759.

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Crystal Structure of Dicarbonyl (η⁵-2, 4-Cyclopentadien-1-yl) tricyclohexylstannyliron

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