The Synthesis and Structure of Large Crystal Cobalt Phosphate from Non-aqueous System

Abstract

Abstract: Large single crystal of (C₂H₁₀N₂)_0.5 CoPO₄ with novel open-framework structure was synthesized from non-aqueous system with ethylene glycol as the solvent.The crystal structure was solved by heavy atomic method and the crystal is monoclinic,space group P2₁/n with α=1.0410 (1) nm,b=0.8947 (1) nm,c=1.0414 (1) nm,β=90.085°,V=0.97002 (12) nm³,Z=4,D_c=1.832 mg·cm^-3,R=0.063.

Key words: Cobalt phosphate, Large single crystal, Non-aqueous system, Crystal structure

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XU Jia-Ning, YUAN Hong-Ming, BU Wei-Ming, SHAO Yi-Ming, SONG Tian-You, FAN Yu-Guo, XU Ru-Ren. The Synthesis and Structure of Large Crystal Cobalt Phosphate from Non-aqueous System[J]. Chem. J. Chinese Universities, 1996, 17(8): 1177.

References

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