Syntheses and Crystal Structures of Two Mononuclear Complexes M(2-SC5H3NH-3-SiMe3)2Cl2(M=Cd,Zn)

Abstract

Abstract: The title complexes,M(2-SC₅H₃NH-3-SiMe₃)₂Cl₂(M=Cd(1),Zn(2)),were synthesized through the reaction of CdCl₂·2.5H₂O(or ZnCl₂) with 3-(trimethylsilyl)-pyridine-2-thiol(TSPT)in methanol,They were characterized by X-ray diffraction analysis,The crystal of compound 1 belongs to the orthorhombic system,with space group Pna2₁,a=2.1472(4)nm,b=1.4453(3)nm,c=0,8049(2)nm,V=2.4980(9)nm³,D_c=1,4629/cm³,Z=4.The final Ris 0.0354 for 1602 reflections[F>4.0σ(F)].The crystal of complex 2 belongs to the orthorhombic system, with space group Fdd2,a=1.7563(4)nm,b=2.9454(6)nm,c=0.9224(2)nm,V=4.772(2) nm³,D_c=1.400 g/cm³,Z=8.The final Ris 0.0237 for 1669 reflections [F>4.0σ(F)].In the two mononuclear complexes, themetal atom is coordinated with two Cl atoms and two Satoms from the sterically hindered thiolate ligands.

Key words: Cadmium thiolate complex, Zinc thiolate complex, Crystal structure, Sterically hindered thiolate ligand

TrendMD:

JIN Xiang-Lin, TANG Ka-Luo, JIA Shao-Juan, TANG You-Qi. Syntheses and Crystal Structures of Two Mononuclear Complexes M(2-SC₅H₃NH-3-SiMe₃)₂Cl₂(M=Cd,Zn)[J]. Chem. J. Chinese Universities, 1996, 17(7): 999.

References

Related Articles 15

[1]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[2]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[3]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[4]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[5]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[6]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[7]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[8]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[9]	TIAN Huan, ZHANG Menglong, WANG Lisha, TONG Bihai, ZHAO Zhuo. Synthesis of 4,13-Dithio Benzene and-18-Crown-6 and Its Selective Extractability on A $g + †$ [J]. Chem. J. Chinese Universities, 2018, 39(6): 1191.
[10]	ZHU Lei,HAN Junyan,CHANG Haizhen,QIU Yuyuan,ZHANG Yanan,PENG Danni,HU Wei,MIAO Shaobin. Different Pathways for the Cyclocondensation Reactions of 1,2-Diamine and 1,2-Diketone^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2686.
[11]	CHEN Qidan, TANG Junjie, FANG Qianrong. Highly Stable Fluorine Containing Hierarchical Porous Covalent Organic Framework^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2357.
[12]	LI Zheng, LI Rui, LI Xia. Synthesis, Crystal Structure and Fluorescent Properties of Transition Metal Complexes Constructed with 2-(3'-Carboxyphenoxy)benzoic Acid and N-Donor Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2363.
[13]	YUN Jixing,HU Zhili,LI Yumeng,JIN Jing,CHEN Chong,YAN Xin,LIU Yonghua,DING Yu,CHI Yuxian,NIU Shuyun. Synthesis, Structure and Photoelectric Property of A Series of Ni(Ⅱ) Complexes Constructed Through Aromatic Carboxylic Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2161.
[14]	TAN Ying, XIAO Mengwu, YE Jiao, HU Aixi, ZENG Ziqing, OU Xiaoming. Synthesis, Crystal Structure and Fungicidal Activity of (Z)-3,3-Dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-one O-[(5-Aryl-1,3,4-oxadiazol-2-yl)methyl] oxime [J]. Chem. J. Chinese Universities, 2017, 38(8): 1375.
[15]	WANG Qiushuang, ZHENG Xiaoli, QU Xianglong, LI Rui, LI Xia. Synthesis, Structure and Luminescence Property of Transition Metal Complexes with 1,3-Di(4-pyridyl)-propane and 1,2-Benzenedicarboxylic Acid^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1125.

Syntheses and Crystal Structures of Two Mononuclear Complexes M(2-SC₅H₃NH-3-SiMe₃)₂Cl₂(M=Cd,Zn)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments