Synthesis and Structure of 1:1 Complex of EthylphenyltinDichloride with N-4-Methoxyphenyl-2-hydroxynaphthylideneimine

Abstract

Abstract: A novel or ganotin complex,EtPhSnCl₂·2HOC₁₀H₆CH=NC₆H₄OCH₃ was syn-thesized,and its crystal struct ure was determined by X-ray diffraction method.The crystalis triclinic,belonging to space group P1 with unit cell parameters a=1.1508(5)nm,b=1.1534(5)nm,c=1.0046(3)nm,a=94,15(3)°,β=115.47(3)°,r=85.94(4)°,V=1.1997(1) nm³,Z=2,D_c=1.68 g/cm³,μ=13.20 cm^-1,F(000)=618 for 4131 reflections.R=0.047,R_w=0.047.The ligand coordinates to tin atom via phenolic oxygen atom.The complex has a distored trigonal bipyramidal structure,the phenolic oxygen atom of theligand and one of two chlorine atoms occupy the axial position. The distance between non-coodinated nitrogen atom with phenolic oxygen atom is0.2574 nm,which indicates that theintramolecular hydrogen bond of Schiff base ligand is retained in the complex.

Key words: Ethylphenyltin dichloride, Schiff base complex, Crystal structure

TrendMD:

LIU Bao-Dian, BAO Ming, SUN Zhen-Gang, HE Qing-Lin, XING Yan, JIA Heng-Qing, LIN Yong-Hua. Synthesis and Structure of 1:1 Complex of EthylphenyltinDichloride with N-4-Methoxyphenyl-2-hydroxynaphthylideneimine[J]. Chem. J. Chinese Universities, 1996, 17(1): 88.

References

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