Synthesis, Crystal Structure and Characterization of [Cu2(C6H5COO)4(C3H4N2S)2]

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (12): 1837.

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Synthesis, Crystal Structure and Characterization of [Cu₂(C₆H₅COO)₄(C₃H₄N₂S)₂]

WANG Dong-Mei¹, YANG Rui-Na¹, JIN Dou-Man¹, LUO Bao-Sheng², CHEN Liao-Rong²

1. Henan institute of Chemistry, Zhengzhou, 450003;
2. Analysis and Measurement Center, Wuhan University, 430072

Received:1995-01-05 Revised:1995-03-22 Online:1995-12-24 Published:1995-12-24

Abstract

Abstract: The metallic copper powder was oxidized by dibenzoyl peroxide in the presence of 2-aminothiazol in acetone resulting in the copper (Ⅱ) complex [Cu₂ (C₆H₅COO)₄(C₃H₄N₂S)₂].Crystal of the complex belongs to monoclinic, space group P2₁/n,with the crystal cell parameters:a = 1.0685 (1)nm, b=1. 9028(6)nm, c=1. 7046 (9) nm:α= γ=90°, β=96. 49(3)°, V= 3.443(4) nm³, Z=4,F(000)=824, D_c=1.5558g/cm³μ=14. 078cm^-1, R=0.04821.R_w= 0. 05314.The complex was also characterized by elementary analy ses, IR, X-ray powder diffraction, and TG.

Key words: Copper complex, Oxidative addition, Crystal structure

TrendMD:

WANG Dong-Mei, YANG Rui-Na, JIN Dou-Man, LUO Bao-Sheng, CHEN Liao-Rong. Synthesis, Crystal Structure and Characterization of [Cu₂(C₆H₅COO)₄(C₃H₄N₂S)₂][J]. Chem. J. Chinese Universities, 1995, 16(12): 1837.

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Synthesis, Crystal Structure and Characterization of [Cu₂(C₆H₅COO)₄(C₃H₄N₂S)₂]

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