Preparation of Tetrathiafulvalene Derivatives Containing Sulfur Substituting Groups from 1, 3, 4, 6-Tetrathiapentalene

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (1): 69.

• Articles • Previous Articles Next Articles

Preparation of Tetrathiafulvalene Derivatives Containing Sulfur Substituting Groups from 1, 3, 4, 6-Tetrathiapentalene

WANG Jian-Hua, YANG Geng-Xin, WANG Gui-Lin, SHI Zhen

Department of Chemistry, Northwest University, Xi'an, 710069

Received:1994-01-17 Revised:1994-05-06 Online:1995-01-24 Published:1995-01-24

Abstract

Abstract: Tetramethylthiotertrathiafulvalene,tetraethylthiotetrathiafulvalene,diquinoxalinylsulfur ether,4-methylthio-5-methoxy-carbonylthio-1, 3-dithiole-2-one,tetrakis(metliylthio) ethylene and 4, 4'-dimethylthio-5, 5'-dimethoxycarbonylthio tetrathiafulvalene have been prepared by means of coupling/alcoholysis/alkylation or alcoholysis/alkylation/coupling, and by using1, 3, 4, 6-tetrathiapentalene-2,5-dione as the starting material. Areasonable mechanism was given for alcoholysis of 1,3,4,6-tetrathiapentalene-2,5-dione.The reason for lack of the expected products was discussed.The electrochemical nature of the three tetrathiafulvalene derivatives prepared was studied by cyclic voltammetry.

Key words: Alkylthiotetrathiafulvalene, Diquinoxalinylsulfur ether, Cyclic voltammogram, Alcohlysis ring-opening, Coupling

TrendMD:

WANG Jian-Hua, YANG Geng-Xin, WANG Gui-Lin, SHI Zhen. Preparation of Tetrathiafulvalene Derivatives Containing Sulfur Substituting Groups from 1, 3, 4, 6-Tetrathiapentalene[J]. Chem. J. Chinese Universities, 1995, 16(1): 69.

[1]	LUO Xinyan, JIA Ruonan, XIANG Yong, ZHANG Xiaokun. Progress on the Stretchable Composite Solid Polymer Electrolytes [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220149.
[2]	WANG Ruhan, JIA Shunhan, WU Limin, SUN Xiaofu, HAN Buxing. CO₂-involved Electrochemical C—N Coupling into Value-added Chemicals [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220395.
[3]	ZHAO Sheng, HUO Zhipeng, ZHONG Guoqiang, ZHANG Hong, HU Liqun. Preparation of Modified Gadolinium/Boron/Polyethylene Nanocomposite and Its Radiation Shielding Performance for Neutron and Gamma-ray [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220039.
[4]	WU Fengtian, LI Jun, SUN Yijia, ZENG Rong, REN Han, LIU Xiuping, ZHANG Caihong, YAN Fangming, WU Ling, CUI Chunna. Fibroin Assisted Copper-promoted C-N Coupling Reaction [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210707.
[5]	BI Gening, XIAO Xiaohua, LI Gongke. Development and Validation of Multiple Physical Fields Coupling Model for Microwave-assisted Extraction [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210739.
[6]	CHEN Wangsong, LUO Lan, LIU Yuguang, ZHOU Hua, KONG Xianggui, LI Zhenhua, DUAN Haohong. Recent Progress in Photoelectrochemical H₂ Production Coupled with Biomass-derived Alcohol/aldehyde Oxidation [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210683.
[7]	LI Weitang, REN Jiajun, SHUAI Zhigang. Theory and Applications of Time Dependent Density Matrix Renormalization Group [J]. Chem. J. Chinese Universities, 2021, 42(7): 2085.
[8]	WANG Jian, ZHANG Hongxing. Theoretical Study on the Structural-photophysical Relationships of Tetra-Pt Phosphorescent Emitters [J]. Chem. J. Chinese Universities, 2021, 42(7): 2245.
[9]	AN Feng, HU Xixi, XIE Daiqian. Research Advances on Nonadiabatic Energy Transfer Dynamics for Triatomic Molecules [J]. Chem. J. Chinese Universities, 2021, 42(7): 2103.
[10]	WU Qiliang, MEI Jinghao, LI Zheng, FAN Haidong, ZHANG Yanwei. Photo-thermal Coupling Water Splitting over Fe-doped TiO₂ with Various Nanostructures [J]. Chem. J. Chinese Universities, 2021, 42(6): 1837.
[11]	SUN Zhetao, HE Yingjie, CHEN Shaojie, NIE Lu, HUANG Yuanqi, LIU Wei. Simulation of the Electrochemistry Process with the Coupling of Multiple Physical Fields for All-solid-state Lithium Batteries [J]. Chem. J. Chinese Universities, 2021, 42(5): 1598.
[12]	WANG Peng, MAO Dan, WAN Jiawei, QI Qi, DU Jiang, WANG Dan. Effect of Hollow Multi-shelled TiO₂ on Mechanical Properties of Epoxy Resin Composites [J]. Chem. J. Chinese Universities, 2021, 42(10): 3218.
[13]	ZHOU Hua, LI Zhenhua, KONG Xianggui, DUAN Haohong. Recent Progress in Electrochemical Catalytic Conversion of Biomass Platform Molecules into High-value Added Fuels and Chemicals^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1449.
[14]	LIU Hengshuo,YU Zhiquan,SUN Zhichao,WANG Yao,LIU Yingya,WANG Anjie. Copper Salt Anchored on a Covalent Organic Framework as Heterogeneous Catalyst for Chan-Lam Coupling Reaction ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1091.
[15]	JIANG Tong, REN Jiajun, SHUAI Zhigang. Frequency Domain Density Matrix Renormalization Group [J]. Chem. J. Chinese Universities, 2020, 41(12): 2610.

Preparation of Tetrathiafulvalene Derivatives Containing Sulfur Substituting Groups from 1, 3, 4, 6-Tetrathiapentalene

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments