Reaction of Lithium Diphenylphosphide with Fulvenes─Syntheses and Characterization of Substituted Ferrocene Derivatives

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (6): 854.

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Reaction of Lithium Diphenylphosphide with Fulvenes─Syntheses and Characterization of Substituted Ferrocene Derivatives

WANG Jia-Xi¹, HE Zheng-Jie¹, CHEN Shou-Shan¹, WANG Xu-Kun¹, WANG Hong-Gen²

1. Institute of Elemento-Organic Chemistry, Nankai University, Tianjin , 300071;
2. Central Lab.of Nankai University

Received:1993-09-14 Revised:1994-02-26 Online:1994-06-24 Published:1994-06-24

Abstract

Abstract: Lithium diphenylphosphide reacted with 6, 6-dimethylfulvene to give addition product, phosphino-substituted cyclopentadienyl anion(I), which complexed with FeCl₂, to form 1, 1′-bis[1-diphenylphosphino-isopropyl) ferrocene(Ⅱ).Compound Ⅱ reacted with PdCl₂, (PhCN)₂, to give heteronuclear metal complex(Ⅲ).The single crystal of Ⅱ is monoclinic, space group P2₁/c with a= 1.3382(5) nm, b=0.8550(1)nm, c=1.7309(4)nm, β-109.16(2)°.V=1.87082 nms, D_x=1.272 g/cm³.μ=5.16 cm^-1, F(000)=378, Z=2. The study on ³¹p NMRshowed complex(Ⅱ)was a fluxional molecule with η⁵η³η¹.

Key words: Phosphino-substituted ferrocene, Fe-Pd dimetal, Crystal structure, Fluxional phenomenon.

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WANG Jia-Xi, HE Zheng-Jie, CHEN Shou-Shan, WANG Xu-Kun, WANG Hong-Gen. Reaction of Lithium Diphenylphosphide with Fulvenes─Syntheses and Characterization of Substituted Ferrocene Derivatives[J]. Chem. J. Chinese Universities, 1994, 15(6): 854.

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Reaction of Lithium Diphenylphosphide with Fulvenes─Syntheses and Characterization of Substituted Ferrocene Derivatives

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