Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (5): 745.

• Articles • Previous Articles     Next Articles

Syntheses and Structures of 17-Electron Pentadienyl Vanadium Carbonyl Complexes

WANG Yue1, LIU Ju-Zheng1, FAN Yu-Guo1, LIANG Ying-Qiu2   

  1. 1. Key Laboratory of Molecular Spectrum and Molecular Structure, Institute of Theoretical Chemistry, Jilin University, Changchun, 130023;
    2. Department of Chemistry, Nanjing university, Nanjing
  • Received:1993-06-22 Revised:1993-11-06 Online:1994-05-24 Published:1994-05-24

Abstract: Using four kinds of methyl pentadienyl ligands,carbonyl complexes of open metallocene vanadocenes,[2,4-(CH3)2C5H5]2VCO(I),[2,3-(CH3)2C5H5]2VCO(I)和[2-CH3C5H6]2VCO(Ⅱ)and[3-CH3C5H6]2VCO(Ⅳ)have been synthesized,in which I,Ⅲand Ⅳ are new complexes.I,Ⅱ,Ⅲ and Ⅳ have been characterized by X-ray diffraction,IRand EPRmethods, Two kinds of phases of Iin solid state have been found.

Key words: Open metallocene metallocene, Pentadienyl, Structure

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